Materials Data on La2B4Rh5 by Materials Project

doi:10.17188/1190839

Title: Materials Data on La2B4Rh5 by Materials Project

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Abstract

La2Rh5B4 crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. La is bonded in a 8-coordinate geometry to ten Rh and six equivalent B atoms. There are a spread of La–Rh bond distances ranging from 3.13–3.31 Å. There are two shorter (3.05 Å) and four longer (3.22 Å) La–B bond lengths. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded in a 4-coordinate geometry to four equivalent La and four equivalent B atoms. All Rh–B bond lengths are 2.14 Å. In the second Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent La and four equivalent B atoms. All Rh–B bond lengths are 2.21 Å. In the third Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent La and four equivalent B atoms. All Rh–B bond lengths are 2.20 Å. B is bonded in a 5-coordinate geometry to three equivalent La and five Rh atoms.

Authors:: The Materials Project

Publication Date:: 2020-07-16

Other Number(s):: mp-14696

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; La2B4Rh5; B-La-Rh

OSTI Identifier:: 1190839

DOI:: https://doi.org/10.17188/1190839

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                    The Materials Project. Materials Data on La2B4Rh5 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1190839.

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                    The Materials Project. Materials Data on La2B4Rh5 by Materials Project.  United States.  doi:https://doi.org/10.17188/1190839

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                    The Materials Project. 2020.  
"Materials Data on La2B4Rh5 by Materials Project".  United States.  doi:https://doi.org/10.17188/1190839.  https://www.osti.gov/servlets/purl/1190839. Pub date:Thu Jul 16 00:00:00 EDT 2020

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@article{osti_1190839,

  title        = {Materials Data on La2B4Rh5 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {La2Rh5B4 crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. La is bonded in a 8-coordinate geometry to ten Rh and six equivalent B atoms. There are a spread of La–Rh bond distances ranging from 3.13–3.31 Å. There are two shorter (3.05 Å) and four longer (3.22 Å) La–B bond lengths. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded in a 4-coordinate geometry to four equivalent La and four equivalent B atoms. All Rh–B bond lengths are 2.14 Å. In the second Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent La and four equivalent B atoms. All Rh–B bond lengths are 2.21 Å. In the third Rh site, Rh is bonded in a distorted square co-planar geometry to four equivalent La and four equivalent B atoms. All Rh–B bond lengths are 2.20 Å. B is bonded in a 5-coordinate geometry to three equivalent La and five Rh atoms.},

  doi          = {10.17188/1190839},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {7}

}

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DOI: https://doi.org/10.17188/1190839

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