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Title: Materials Data on AgSb2F12 by Materials Project

Abstract

Ag(SbF6)2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one Ag(SbF6)2 sheet oriented in the (0, 0, 1) direction. Ag2+ is bonded to six F1- atoms to form AgF6 octahedra that share corners with six equivalent SbF6 octahedra. The corner-sharing octahedra tilt angles range from 32–45°. There are a spread of Ag–F bond distances ranging from 2.16–2.56 Å. Sb5+ is bonded to six F1- atoms to form SbF6 octahedra that share corners with three equivalent AgF6 octahedra. The corner-sharing octahedra tilt angles range from 32–45°. There are a spread of Sb–F bond distances ranging from 1.88–2.02 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ag2+ and one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ag2+ and one Sb5+ atom. In the fifth F1- site, F1- is bonded in a distorted bent 150 degrees geometrymore » to one Ag2+ and one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.« less

Publication Date:
Other Number(s):
mp-14653
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AgSb2F12; Ag-F-Sb
OSTI Identifier:
1190827
DOI:
https://doi.org/10.17188/1190827

Citation Formats

The Materials Project. Materials Data on AgSb2F12 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1190827.
The Materials Project. Materials Data on AgSb2F12 by Materials Project. United States. doi:https://doi.org/10.17188/1190827
The Materials Project. 2020. "Materials Data on AgSb2F12 by Materials Project". United States. doi:https://doi.org/10.17188/1190827. https://www.osti.gov/servlets/purl/1190827. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1190827,
title = {Materials Data on AgSb2F12 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag(SbF6)2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one Ag(SbF6)2 sheet oriented in the (0, 0, 1) direction. Ag2+ is bonded to six F1- atoms to form AgF6 octahedra that share corners with six equivalent SbF6 octahedra. The corner-sharing octahedra tilt angles range from 32–45°. There are a spread of Ag–F bond distances ranging from 2.16–2.56 Å. Sb5+ is bonded to six F1- atoms to form SbF6 octahedra that share corners with three equivalent AgF6 octahedra. The corner-sharing octahedra tilt angles range from 32–45°. There are a spread of Sb–F bond distances ranging from 1.88–2.02 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ag2+ and one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ag2+ and one Sb5+ atom. In the fifth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ag2+ and one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.},
doi = {10.17188/1190827},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}