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Title: Materials Data on P2W by Materials Project

Abstract

WP2 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional. W6+ is bonded to seven P3- atoms to form a mixture of distorted corner, edge, and face-sharing WP7 pentagonal bipyramids. There are five shorter (2.50 Å) and two longer (2.51 Å) W–P bond lengths. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 5-coordinate geometry to four equivalent W6+ and one P3- atom. The P–P bond length is 2.17 Å. In the second P3- site, P3- is bonded in a distorted rectangular see-saw-like geometry to three equivalent W6+ and one P3- atom.

Publication Date:
Other Number(s):
mp-11328
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; P2W; P-W
OSTI Identifier:
1187741
DOI:
https://doi.org/10.17188/1187741

Citation Formats

The Materials Project. Materials Data on P2W by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1187741.
The Materials Project. Materials Data on P2W by Materials Project. United States. doi:https://doi.org/10.17188/1187741
The Materials Project. 2020. "Materials Data on P2W by Materials Project". United States. doi:https://doi.org/10.17188/1187741. https://www.osti.gov/servlets/purl/1187741. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1187741,
title = {Materials Data on P2W by Materials Project},
author = {The Materials Project},
abstractNote = {WP2 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional. W6+ is bonded to seven P3- atoms to form a mixture of distorted corner, edge, and face-sharing WP7 pentagonal bipyramids. There are five shorter (2.50 Å) and two longer (2.51 Å) W–P bond lengths. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 5-coordinate geometry to four equivalent W6+ and one P3- atom. The P–P bond length is 2.17 Å. In the second P3- site, P3- is bonded in a distorted rectangular see-saw-like geometry to three equivalent W6+ and one P3- atom.},
doi = {10.17188/1187741},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}