U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on P2W by Materials Project
Abstract
WP2 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional. W6+ is bonded to seven P3- atoms to form a mixture of distorted corner, edge, and face-sharing WP7 pentagonal bipyramids. There are five shorter (2.50 Å) and two longer (2.51 Å) W–P bond lengths. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 5-coordinate geometry to four equivalent W6+ and one P3- atom. The P–P bond length is 2.17 Å. In the second P3- site, P3- is bonded in a distorted rectangular see-saw-like geometry to three equivalent W6+ and one P3- atom.
- Publication Date:
- Other Number(s):
- mp-11328
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; P-W; P2W; crystal structure
- OSTI Identifier:
- 1187741
- DOI:
- https://doi.org/10.17188/1187741
Citation Formats
Materials Data on P2W by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1187741.
Materials Data on P2W by Materials Project. United States. doi:https://doi.org/10.17188/1187741
2020.
"Materials Data on P2W by Materials Project". United States. doi:https://doi.org/10.17188/1187741. https://www.osti.gov/servlets/purl/1187741. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1187741,
title = {Materials Data on P2W by Materials Project},
abstractNote = {WP2 crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional. W6+ is bonded to seven P3- atoms to form a mixture of distorted corner, edge, and face-sharing WP7 pentagonal bipyramids. There are five shorter (2.50 Å) and two longer (2.51 Å) W–P bond lengths. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 5-coordinate geometry to four equivalent W6+ and one P3- atom. The P–P bond length is 2.17 Å. In the second P3- site, P3- is bonded in a distorted rectangular see-saw-like geometry to three equivalent W6+ and one P3- atom.},
doi = {10.17188/1187741},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}
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