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Title: Materials Data on K3SbO4 by Materials Project

Abstract

K3SbO4 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. there are three inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a distorted bent 150 degrees geometry to four O2- atoms. There are two shorter (2.53 Å) and two longer (3.09 Å) K–O bond lengths. In the second K1+ site, K1+ is bonded in a distorted hexagonal planar geometry to six O2- atoms. There are a spread of K–O bond distances ranging from 2.71–2.76 Å. In the third K1+ site, K1+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of K–O bond distances ranging from 2.62–2.97 Å. Sb5+ is bonded to six O2- atoms to form edge-sharing SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 1.98–2.13 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 6-coordinate geometry to four K1+ and two equivalent Sb5+ atoms. In the second O2- site, O2- is bonded in a 5-coordinate geometry to four K1+ and one Sb5+ atom.

Publication Date:
Other Number(s):
mp-10543
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; K3SbO4; K-O-Sb
OSTI Identifier:
1187190
DOI:
https://doi.org/10.17188/1187190

Citation Formats

The Materials Project. Materials Data on K3SbO4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1187190.
The Materials Project. Materials Data on K3SbO4 by Materials Project. United States. doi:https://doi.org/10.17188/1187190
The Materials Project. 2020. "Materials Data on K3SbO4 by Materials Project". United States. doi:https://doi.org/10.17188/1187190. https://www.osti.gov/servlets/purl/1187190. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1187190,
title = {Materials Data on K3SbO4 by Materials Project},
author = {The Materials Project},
abstractNote = {K3SbO4 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. there are three inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a distorted bent 150 degrees geometry to four O2- atoms. There are two shorter (2.53 Å) and two longer (3.09 Å) K–O bond lengths. In the second K1+ site, K1+ is bonded in a distorted hexagonal planar geometry to six O2- atoms. There are a spread of K–O bond distances ranging from 2.71–2.76 Å. In the third K1+ site, K1+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of K–O bond distances ranging from 2.62–2.97 Å. Sb5+ is bonded to six O2- atoms to form edge-sharing SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 1.98–2.13 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 6-coordinate geometry to four K1+ and two equivalent Sb5+ atoms. In the second O2- site, O2- is bonded in a 5-coordinate geometry to four K1+ and one Sb5+ atom.},
doi = {10.17188/1187190},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}