U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Zn(ReO4)2 by Materials Project
Abstract
Zn(ReO4)2 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one Zn(ReO4)2 sheet oriented in the (0, 0, 1) direction. Re7+ is bonded to four O2- atoms to form ReO4 tetrahedra that share corners with three equivalent ZnO6 octahedra. The corner-sharing octahedral tilt angles are 17°. There is one shorter (1.73 Å) and three longer (1.76 Å) Re–O bond length. Zn2+ is bonded to six equivalent O2- atoms to form ZnO6 octahedra that share corners with six equivalent ReO4 tetrahedra. All Zn–O bond lengths are 2.09 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a distorted linear geometry to one Re7+ and one Zn2+ atom.
- Publication Date:
- Other Number(s):
- mp-10326
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; O-Re-Zn; Zn(ReO4)2; crystal structure
- OSTI Identifier:
- 1186962
- DOI:
- https://doi.org/10.17188/1186962
Citation Formats
Materials Data on Zn(ReO4)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1186962.
Materials Data on Zn(ReO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1186962
2020.
"Materials Data on Zn(ReO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1186962. https://www.osti.gov/servlets/purl/1186962. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1186962,
title = {Materials Data on Zn(ReO4)2 by Materials Project},
abstractNote = {Zn(ReO4)2 crystallizes in the trigonal P-3 space group. The structure is two-dimensional and consists of one Zn(ReO4)2 sheet oriented in the (0, 0, 1) direction. Re7+ is bonded to four O2- atoms to form ReO4 tetrahedra that share corners with three equivalent ZnO6 octahedra. The corner-sharing octahedral tilt angles are 17°. There is one shorter (1.73 Å) and three longer (1.76 Å) Re–O bond length. Zn2+ is bonded to six equivalent O2- atoms to form ZnO6 octahedra that share corners with six equivalent ReO4 tetrahedra. All Zn–O bond lengths are 2.09 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Re7+ atom. In the second O2- site, O2- is bonded in a distorted linear geometry to one Re7+ and one Zn2+ atom.},
doi = {10.17188/1186962},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}