U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on V3Te4 by Materials Project
Abstract
V3Te4 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent V+2.67+ sites. In the first V+2.67+ site, V+2.67+ is bonded to six Te2- atoms to form a mixture of edge, face, and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 52–54°. There are a spread of V–Te bond distances ranging from 2.71–2.88 Å. In the second V+2.67+ site, V+2.67+ is bonded to six Te2- atoms to form a mixture of edge, face, and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 52–54°. There are two shorter (2.76 Å) and four longer (2.81 Å) V–Te bond lengths. There are two inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a distorted rectangular see-saw-like geometry to four V+2.67+ atoms. In the second Te2- site, Te2- is bonded in a 5-coordinate geometry to five V+2.67+ atoms.
- Publication Date:
- Other Number(s):
- mp-1028
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Te-V; V3Te4; crystal structure
- OSTI Identifier:
- 1186871
- DOI:
- https://doi.org/10.17188/1186871
Citation Formats
Materials Data on V3Te4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1186871.
Materials Data on V3Te4 by Materials Project. United States. doi:https://doi.org/10.17188/1186871
2020.
"Materials Data on V3Te4 by Materials Project". United States. doi:https://doi.org/10.17188/1186871. https://www.osti.gov/servlets/purl/1186871. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1186871,
title = {Materials Data on V3Te4 by Materials Project},
abstractNote = {V3Te4 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent V+2.67+ sites. In the first V+2.67+ site, V+2.67+ is bonded to six Te2- atoms to form a mixture of edge, face, and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 52–54°. There are a spread of V–Te bond distances ranging from 2.71–2.88 Å. In the second V+2.67+ site, V+2.67+ is bonded to six Te2- atoms to form a mixture of edge, face, and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 52–54°. There are two shorter (2.76 Å) and four longer (2.81 Å) V–Te bond lengths. There are two inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a distorted rectangular see-saw-like geometry to four V+2.67+ atoms. In the second Te2- site, Te2- is bonded in a 5-coordinate geometry to five V+2.67+ atoms.},
doi = {10.17188/1186871},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}