U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on H12RhC8NO6 by Materials Project
Abstract
Rh(C2O3)2N(CH3)4 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four Rh(C2O3)2 clusters. In each Rh(C2O3)2 cluster, Rh3+ is bonded in a rectangular see-saw-like geometry to two C and two O2- atoms. Both Rh–C bond lengths are 1.85 Å. Both Rh–O bond lengths are 2.08 Å. There are four inequivalent C sites. In the first C site, C is bonded in a distorted bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.31 Å) C–O bond length. In the second C site, C is bonded in a distorted bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.30 Å) C–O bond length. In the third C site, C is bonded in a linear geometry to one Rh3+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C site, C is bonded in a distorted linear geometry to one Rh3+ and one O2- atom. The C–O bond length is 1.16 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degreesmore »
- Publication Date:
- Other Number(s):
- mp-555813
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; C-H-N-O-Rh; H12RhC8NO6; crystal structure
- OSTI Identifier:
- 1183916
- DOI:
- https://doi.org/10.17188/1183916
Citation Formats
Materials Data on H12RhC8NO6 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1183916.
Materials Data on H12RhC8NO6 by Materials Project. United States. doi:https://doi.org/10.17188/1183916
2020.
"Materials Data on H12RhC8NO6 by Materials Project". United States. doi:https://doi.org/10.17188/1183916. https://www.osti.gov/servlets/purl/1183916. Pub date:Sat May 30 00:00:00 EDT 2020
@article{osti_1183916,
title = {Materials Data on H12RhC8NO6 by Materials Project},
abstractNote = {Rh(C2O3)2N(CH3)4 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four Rh(C2O3)2 clusters. In each Rh(C2O3)2 cluster, Rh3+ is bonded in a rectangular see-saw-like geometry to two C and two O2- atoms. Both Rh–C bond lengths are 1.85 Å. Both Rh–O bond lengths are 2.08 Å. There are four inequivalent C sites. In the first C site, C is bonded in a distorted bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.31 Å) C–O bond length. In the second C site, C is bonded in a distorted bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.30 Å) C–O bond length. In the third C site, C is bonded in a linear geometry to one Rh3+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C site, C is bonded in a distorted linear geometry to one Rh3+ and one O2- atom. The C–O bond length is 1.16 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one C atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C atom. In the third O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one C atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one C atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one C atom.},
doi = {10.17188/1183916},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}