U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Li2V3SbO8 by Materials Project
Abstract
Li2V3SbO8 is Spinel-derived structured and crystallizes in the cubic P4_332 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with three equivalent SbO6 octahedra and corners with nine equivalent VO6 octahedra. The corner-sharing octahedra tilt angles range from 57–61°. All Li–O bond lengths are 2.05 Å. V5+ is bonded to six O2- atoms to form VO6 octahedra that share corners with six equivalent LiO4 tetrahedra, edges with two equivalent SbO6 octahedra, and edges with four equivalent VO6 octahedra. There are a spread of V–O bond distances ranging from 2.02–2.11 Å. Sb1- is bonded to six equivalent O2- atoms to form SbO6 octahedra that share corners with six equivalent LiO4 tetrahedra and edges with six equivalent VO6 octahedra. All Sb–O bond lengths are 2.03 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to one Li1+, two equivalent V5+, and one Sb1- atom. In the second O2- site, O2- is bonded to one Li1+ and three equivalent V5+ atoms to form distorted corner-sharing OLiV3 trigonal pyramids.
- Authors:
- Publication Date:
- Other Number(s):
- mp-849570
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Li2V3SbO8; Li-O-Sb-V
- OSTI Identifier:
- 1308339
- DOI:
- https://doi.org/10.17188/1308339
Citation Formats
The Materials Project. Materials Data on Li2V3SbO8 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1308339.
The Materials Project. Materials Data on Li2V3SbO8 by Materials Project. United States. doi:https://doi.org/10.17188/1308339
The Materials Project. 2020.
"Materials Data on Li2V3SbO8 by Materials Project". United States. doi:https://doi.org/10.17188/1308339. https://www.osti.gov/servlets/purl/1308339. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1308339,
title = {Materials Data on Li2V3SbO8 by Materials Project},
author = {The Materials Project},
abstractNote = {Li2V3SbO8 is Spinel-derived structured and crystallizes in the cubic P4_332 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with three equivalent SbO6 octahedra and corners with nine equivalent VO6 octahedra. The corner-sharing octahedra tilt angles range from 57–61°. All Li–O bond lengths are 2.05 Å. V5+ is bonded to six O2- atoms to form VO6 octahedra that share corners with six equivalent LiO4 tetrahedra, edges with two equivalent SbO6 octahedra, and edges with four equivalent VO6 octahedra. There are a spread of V–O bond distances ranging from 2.02–2.11 Å. Sb1- is bonded to six equivalent O2- atoms to form SbO6 octahedra that share corners with six equivalent LiO4 tetrahedra and edges with six equivalent VO6 octahedra. All Sb–O bond lengths are 2.03 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted rectangular see-saw-like geometry to one Li1+, two equivalent V5+, and one Sb1- atom. In the second O2- site, O2- is bonded to one Li1+ and three equivalent V5+ atoms to form distorted corner-sharing OLiV3 trigonal pyramids.},
doi = {10.17188/1308339},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Apr 30 00:00:00 EDT 2020},
month = {Thu Apr 30 00:00:00 EDT 2020}
}