Materials Data on Rb2O by Materials Project

doi:10.17188/1304534

Title: Materials Data on Rb2O by Materials Project

Dataset
Other Related Research

Abstract

Rb2O is Baddeleyite-like structured and crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded to four equivalent O2- atoms to form a mixture of corner and edge-sharing RbO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.91–2.98 Å. In the second Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.83–2.92 Å. O2- is bonded to seven Rb1+ atoms to form a mixture of distorted corner and edge-sharing ORb7 pentagonal bipyramids.

Authors:: The Materials Project

Publication Date:: Sun May 03 00:00:00 EDT 2020

Other Number(s):: mp-776890

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Rb2O; O-Rb

OSTI Identifier:: 1304534

DOI:: https://doi.org/10.17188/1304534

Citation Formats


                    The Materials Project. Materials Data on Rb2O by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1304534.

Copy to clipboard


                    The Materials Project. Materials Data on Rb2O by Materials Project.  United States.  doi:https://doi.org/10.17188/1304534

Copy to clipboard


                    The Materials Project. 2020.  
"Materials Data on Rb2O by Materials Project".  United States.  doi:https://doi.org/10.17188/1304534.  https://www.osti.gov/servlets/purl/1304534. Pub date:Sun May 03 00:00:00 EDT 2020

Copy to clipboard


                    
@article{osti_1304534,

  title        = {Materials Data on Rb2O by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Rb2O is Baddeleyite-like structured and crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded to four equivalent O2- atoms to form a mixture of corner and edge-sharing RbO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.91–2.98 Å. In the second Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.83–2.92 Å. O2- is bonded to seven Rb1+ atoms to form a mixture of distorted corner and edge-sharing ORb7 pentagonal bipyramids.},

  doi          = {10.17188/1304534},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Sun May 03 00:00:00 EDT 2020},

  month        = {Sun May 03 00:00:00 EDT 2020}

}

Copy to clipboard

Dataset:

View Dataset

DOI: https://doi.org/10.17188/1304534

Save / Share:

Export Metadata

Save to My Library

Similar records in DOE Data Explorer and OSTI.GOV collections:

Materials Data on Rb2O by Materials Project

Dataset The Materials Project

Rb2O is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to four equivalent O2- atoms to form a mixture of edge and corner-sharing RbO4 tetrahedra. All Rb–O bond lengths are 2.98 Å. O2- is bonded in a body-centered cubic geometry to eight equivalent Rb1+ atoms.
Materials Data on Rb2O by Materials Project

Dataset The Materials Project

Rb2O crystallizes in the trigonal R-3m space group. The structure is two-dimensional and consists of three Rb2O sheets oriented in the (0, 0, 1) direction. Rb1+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent O2- atoms. All Rb–O bond lengths are 2.80 Å. O2- is bonded to six equivalent Rb1+ atoms to form distorted edge-sharing ORb6 octahedra.
Materials Data on Rb2O by Materials Project

Dataset The Materials Project

Rb2O is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent O2- atoms. There are one shorter (2.75 Å) and two longer (3.05 Å) Rb–O bond lengths. In the second Rb1+ site, Rb1+ is bonded to four equivalent O2- atoms to form a mixture of edge and corner-sharing RbO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.87–2.99 Å. O2- is bonded in a 7-coordinate geometry to seven Rb1+more » atoms.« less
Materials Data on Rb2O by Materials Project

Dataset The Materials Project

Rb2O is Hydrophilite-like structured and crystallizes in the monoclinic P2_1 space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.81–2.90 Å. In the second Rb1+ site, Rb1+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. There are two shorter (2.81 Å) and one longer (2.92 Å) Rb–O bond lengths. O2- is bonded to six Rb1+ atoms to form a mixture of edge and corner-sharing ORb6more »« less
Materials Data on Rb2O by Materials Project

Dataset The Materials Project

Rb2O is trigonal omega structured and crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of one Rb2O sheet oriented in the (1, 0, 0) direction. there are six inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a distorted trigonal non-coplanar geometry to three O2- atoms. There are a spread of Rb–O bond distances ranging from 2.78–2.82 Å. In the second Rb1+ site, Rb1+ is bonded in a distorted trigonal non-coplanar geometry to three O2- atoms. There are a spread of Rb–O bond distances ranging from 2.78–2.82 Å. In the third Rb1+more »« less

Similar Records