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Title: Materials Data on LiSbO3 by Materials Project

Abstract

LiSbO3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with eight equivalent SbO6 octahedra and an edgeedge with one LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 58–62°. There are a spread of Li–O bond distances ranging from 1.98–2.16 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent LiO4 tetrahedra and edges with three equivalent SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.01–2.05 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+ and two equivalent Sb5+ atoms to form distorted edge-sharing OLi2Sb2 tetrahedra. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-770932
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; LiSbO3; Li-O-Sb
OSTI Identifier:
1300189
DOI:
https://doi.org/10.17188/1300189

Citation Formats

The Materials Project. Materials Data on LiSbO3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1300189.
The Materials Project. Materials Data on LiSbO3 by Materials Project. United States. doi:https://doi.org/10.17188/1300189
The Materials Project. 2020. "Materials Data on LiSbO3 by Materials Project". United States. doi:https://doi.org/10.17188/1300189. https://www.osti.gov/servlets/purl/1300189. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1300189,
title = {Materials Data on LiSbO3 by Materials Project},
author = {The Materials Project},
abstractNote = {LiSbO3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 tetrahedra that share corners with eight equivalent SbO6 octahedra and an edgeedge with one LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 58–62°. There are a spread of Li–O bond distances ranging from 1.98–2.16 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight equivalent LiO4 tetrahedra and edges with three equivalent SbO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.01–2.05 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Li1+ and two equivalent Sb5+ atoms to form distorted edge-sharing OLi2Sb2 tetrahedra. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+ and two equivalent Sb5+ atoms.},
doi = {10.17188/1300189},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}