U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Ce2SbO2 by Materials Project
Abstract
Ce2SbO2 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 4-coordinate geometry to four equivalent Sb2- and four O2- atoms. There are a spread of Ce–Sb bond distances ranging from 3.35–3.49 Å. There are two shorter (2.33 Å) and two longer (2.34 Å) Ce–O bond lengths. In the second Ce3+ site, Ce3+ is bonded in a 4-coordinate geometry to four equivalent Sb2- and four O2- atoms. There are a spread of Ce–Sb bond distances ranging from 3.37–3.54 Å. There are two shorter (2.33 Å) and two longer (2.34 Å) Ce–O bond lengths. Sb2- is bonded in a body-centered cubic geometry to eight Ce3+ atoms. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four Ce3+ atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra. In the second O2- site, O2- is bonded to four Ce3+ atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra.
- Authors:
- Publication Date:
- Other Number(s):
- mp-685137
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Ce2SbO2; Ce-O-Sb
- OSTI Identifier:
- 1284109
- DOI:
- https://doi.org/10.17188/1284109
Citation Formats
The Materials Project. Materials Data on Ce2SbO2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1284109.
The Materials Project. Materials Data on Ce2SbO2 by Materials Project. United States. doi:https://doi.org/10.17188/1284109
The Materials Project. 2020.
"Materials Data on Ce2SbO2 by Materials Project". United States. doi:https://doi.org/10.17188/1284109. https://www.osti.gov/servlets/purl/1284109. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1284109,
title = {Materials Data on Ce2SbO2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce2SbO2 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 4-coordinate geometry to four equivalent Sb2- and four O2- atoms. There are a spread of Ce–Sb bond distances ranging from 3.35–3.49 Å. There are two shorter (2.33 Å) and two longer (2.34 Å) Ce–O bond lengths. In the second Ce3+ site, Ce3+ is bonded in a 4-coordinate geometry to four equivalent Sb2- and four O2- atoms. There are a spread of Ce–Sb bond distances ranging from 3.37–3.54 Å. There are two shorter (2.33 Å) and two longer (2.34 Å) Ce–O bond lengths. Sb2- is bonded in a body-centered cubic geometry to eight Ce3+ atoms. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four Ce3+ atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra. In the second O2- site, O2- is bonded to four Ce3+ atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra.},
doi = {10.17188/1284109},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 23 00:00:00 EDT 2020},
month = {Thu Jul 23 00:00:00 EDT 2020}
}