U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sn(PO3)3 by Materials Project
Abstract
Sn(PO3)3 crystallizes in the hexagonal P-6c2 space group. The structure is three-dimensional. Sn3+ is bonded to six equivalent O2- atoms to form SnO6 octahedra that share corners with six equivalent PO4 tetrahedra. All Sn–O bond lengths are 2.24 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent SnO6 octahedra and corners with two equivalent PO4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. There is two shorter (1.51 Å) and two longer (1.61 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent P5+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn3+ and one P5+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-673129
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sn(PO3)3; O-P-Sn
- OSTI Identifier:
- 1282341
- DOI:
- https://doi.org/10.17188/1282341
Citation Formats
The Materials Project. Materials Data on Sn(PO3)3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1282341.
The Materials Project. Materials Data on Sn(PO3)3 by Materials Project. United States. doi:https://doi.org/10.17188/1282341
The Materials Project. 2020.
"Materials Data on Sn(PO3)3 by Materials Project". United States. doi:https://doi.org/10.17188/1282341. https://www.osti.gov/servlets/purl/1282341. Pub date:Fri May 01 00:00:00 EDT 2020
@article{osti_1282341,
title = {Materials Data on Sn(PO3)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Sn(PO3)3 crystallizes in the hexagonal P-6c2 space group. The structure is three-dimensional. Sn3+ is bonded to six equivalent O2- atoms to form SnO6 octahedra that share corners with six equivalent PO4 tetrahedra. All Sn–O bond lengths are 2.24 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent SnO6 octahedra and corners with two equivalent PO4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. There is two shorter (1.51 Å) and two longer (1.61 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent P5+ atoms. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Sn3+ and one P5+ atom.},
doi = {10.17188/1282341},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri May 01 00:00:00 EDT 2020},
month = {Fri May 01 00:00:00 EDT 2020}
}