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Title: Materials Data on LiLa2SbO6 by Materials Project

Abstract

La2LiSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Li1+ is bonded to six O2- atoms to form LiO6 octahedra that share corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are a spread of Li–O bond distances ranging from 2.18–2.21 Å. La3+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of La–O bond distances ranging from 2.41–2.89 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with six equivalent LiO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are four shorter (2.01 Å) and two longer (2.02 Å) Sb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to one Li1+, two equivalent La3+, and one Sb5+ atom to form distorted corner-sharing OLiLa2Sb tetrahedra. In the second O2- site, O2- is bonded in a 5-coordinate geometry to one Li1+, three equivalent La3+, and one Sb5+ atom. In the third O2- site, O2- is bonded in a 5-coordinate geometry to one Li1+, three equivalent La3+, and one Sb5+ atom.

Authors:
Publication Date:
Other Number(s):
mp-6674
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; LiLa2SbO6; La-Li-O-Sb
OSTI Identifier:
1281534
DOI:
https://doi.org/10.17188/1281534

Citation Formats

The Materials Project. Materials Data on LiLa2SbO6 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1281534.
The Materials Project. Materials Data on LiLa2SbO6 by Materials Project. United States. doi:https://doi.org/10.17188/1281534
The Materials Project. 2020. "Materials Data on LiLa2SbO6 by Materials Project". United States. doi:https://doi.org/10.17188/1281534. https://www.osti.gov/servlets/purl/1281534. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1281534,
title = {Materials Data on LiLa2SbO6 by Materials Project},
author = {The Materials Project},
abstractNote = {La2LiSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Li1+ is bonded to six O2- atoms to form LiO6 octahedra that share corners with six equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are a spread of Li–O bond distances ranging from 2.18–2.21 Å. La3+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of La–O bond distances ranging from 2.41–2.89 Å. Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with six equivalent LiO6 octahedra. The corner-sharing octahedra tilt angles range from 30–33°. There are four shorter (2.01 Å) and two longer (2.02 Å) Sb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to one Li1+, two equivalent La3+, and one Sb5+ atom to form distorted corner-sharing OLiLa2Sb tetrahedra. In the second O2- site, O2- is bonded in a 5-coordinate geometry to one Li1+, three equivalent La3+, and one Sb5+ atom. In the third O2- site, O2- is bonded in a 5-coordinate geometry to one Li1+, three equivalent La3+, and one Sb5+ atom.},
doi = {10.17188/1281534},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}