Materials Data on K2Pt(CN)4 by Materials Project

doi:10.17188/1279627

Title: Materials Data on K2Pt(CN)4 by Materials Project

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Abstract

K2Pt(CN)4 crystallizes in the orthorhombic Pccn space group. The structure is three-dimensional. K1+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of K–N bond distances ranging from 2.75–3.27 Å. Pt2+ is bonded in a distorted square co-planar geometry to four C2+ atoms. There is two shorter (1.98 Å) and two longer (2.00 Å) Pt–C bond length. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent K1+ and one C2+ atom. In the second N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent K1+ and one C2+ atom.

Authors:: The Materials Project

Publication Date:: Thu Apr 30 00:00:00 EDT 2020

Other Number(s):: mp-637196

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; K2Pt(CN)4; C-K-N-Pt

OSTI Identifier:: 1279627

DOI:: https://doi.org/10.17188/1279627

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                    The Materials Project. Materials Data on K2Pt(CN)4 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1279627.

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                    The Materials Project. Materials Data on K2Pt(CN)4 by Materials Project.  United States.  doi:https://doi.org/10.17188/1279627

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                    The Materials Project. 2020.  
"Materials Data on K2Pt(CN)4 by Materials Project".  United States.  doi:https://doi.org/10.17188/1279627.  https://www.osti.gov/servlets/purl/1279627. Pub date:Thu Apr 30 00:00:00 EDT 2020

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@article{osti_1279627,

  title        = {Materials Data on K2Pt(CN)4 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {K2Pt(CN)4 crystallizes in the orthorhombic Pccn space group. The structure is three-dimensional. K1+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of K–N bond distances ranging from 2.75–3.27 Å. Pt2+ is bonded in a distorted square co-planar geometry to four C2+ atoms. There is two shorter (1.98 Å) and two longer (2.00 Å) Pt–C bond length. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent K1+ and one C2+ atom. In the second N3- site, N3- is bonded in a 1-coordinate geometry to three equivalent K1+ and one C2+ atom.},

  doi          = {10.17188/1279627},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Apr 30 00:00:00 EDT 2020},

  month        = {Thu Apr 30 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1279627

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