Materials Data on Rb2Hg2PdCl8 by Materials Project
Abstract
Rb2PdHg2Cl8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.44–3.87 Å. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Hg2+ is bonded in a 2-coordinate geometry to five Cl1- atoms. There are a spread of Hg–Cl bond distances ranging from 2.35–3.27 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted single-bond geometry to two equivalent Rb1+ and two equivalent Hg2+ atoms. In the second Cl1- site, Cl1- is bonded to three equivalent Rb1+, one Pd2+, and one Hg2+ atom to form a mixture of distorted corner, edge, and face-sharing ClRb3HgPd square pyramids. In the third Cl1- site, Cl1- is bonded in a distorted single-bond geometry to two equivalent Rb1+ and one Hg2+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-568252
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Rb2Hg2PdCl8; Cl-Hg-Pd-Rb
- OSTI Identifier:
- 1274331
- DOI:
- https://doi.org/10.17188/1274331
Citation Formats
The Materials Project. Materials Data on Rb2Hg2PdCl8 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1274331.
The Materials Project. Materials Data on Rb2Hg2PdCl8 by Materials Project. United States. doi:https://doi.org/10.17188/1274331
The Materials Project. 2020.
"Materials Data on Rb2Hg2PdCl8 by Materials Project". United States. doi:https://doi.org/10.17188/1274331. https://www.osti.gov/servlets/purl/1274331. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1274331,
title = {Materials Data on Rb2Hg2PdCl8 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb2PdHg2Cl8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Rb1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.44–3.87 Å. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Hg2+ is bonded in a 2-coordinate geometry to five Cl1- atoms. There are a spread of Hg–Cl bond distances ranging from 2.35–3.27 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted single-bond geometry to two equivalent Rb1+ and two equivalent Hg2+ atoms. In the second Cl1- site, Cl1- is bonded to three equivalent Rb1+, one Pd2+, and one Hg2+ atom to form a mixture of distorted corner, edge, and face-sharing ClRb3HgPd square pyramids. In the third Cl1- site, Cl1- is bonded in a distorted single-bond geometry to two equivalent Rb1+ and one Hg2+ atom.},
doi = {10.17188/1274331},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 14 00:00:00 EDT 2020},
month = {Tue Jul 14 00:00:00 EDT 2020}
}