Materials Data on P3N5 by Materials Project
Abstract
P3N5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four N3- atoms to form corner-sharing PN4 tetrahedra. There is two shorter (1.57 Å) and two longer (1.68 Å) P–N bond length. In the second P5+ site, P5+ is bonded to four N3- atoms to form a mixture of edge and corner-sharing PN4 tetrahedra. There are a spread of P–N bond distances ranging from 1.56–1.72 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted trigonal planar geometry to three P5+ atoms. In the second N3- site, N3- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the third N3- site, N3- is bonded in a linear geometry to two equivalent P5+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-567907
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; P3N5; N-P
- OSTI Identifier:
- 1274118
- DOI:
- https://doi.org/10.17188/1274118
Citation Formats
The Materials Project. Materials Data on P3N5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1274118.
The Materials Project. Materials Data on P3N5 by Materials Project. United States. doi:https://doi.org/10.17188/1274118
The Materials Project. 2020.
"Materials Data on P3N5 by Materials Project". United States. doi:https://doi.org/10.17188/1274118. https://www.osti.gov/servlets/purl/1274118. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1274118,
title = {Materials Data on P3N5 by Materials Project},
author = {The Materials Project},
abstractNote = {P3N5 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four N3- atoms to form corner-sharing PN4 tetrahedra. There is two shorter (1.57 Å) and two longer (1.68 Å) P–N bond length. In the second P5+ site, P5+ is bonded to four N3- atoms to form a mixture of edge and corner-sharing PN4 tetrahedra. There are a spread of P–N bond distances ranging from 1.56–1.72 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted trigonal planar geometry to three P5+ atoms. In the second N3- site, N3- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the third N3- site, N3- is bonded in a linear geometry to two equivalent P5+ atoms.},
doi = {10.17188/1274118},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 15 00:00:00 EDT 2020},
month = {Wed Jul 15 00:00:00 EDT 2020}
}