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Title: Materials Data on SmBi2IO4 by Materials Project

Abstract

SmBi2O4I is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Sm3+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Sm–O bond lengths are 2.46 Å. Bi3+ is bonded in a 4-coordinate geometry to four equivalent O2- and four equivalent I1- atoms. All Bi–O bond lengths are 2.27 Å. All Bi–I bond lengths are 3.67 Å. O2- is bonded to two equivalent Sm3+ and two equivalent Bi3+ atoms to form a mixture of corner and edge-sharing OSm2Bi2 tetrahedra. I1- is bonded in a distorted body-centered cubic geometry to eight equivalent Bi3+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-552292
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SmBi2IO4; Bi-I-O-Sm
OSTI Identifier:
1267567
DOI:
https://doi.org/10.17188/1267567

Citation Formats

The Materials Project. Materials Data on SmBi2IO4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1267567.
The Materials Project. Materials Data on SmBi2IO4 by Materials Project. United States. doi:https://doi.org/10.17188/1267567
The Materials Project. 2020. "Materials Data on SmBi2IO4 by Materials Project". United States. doi:https://doi.org/10.17188/1267567. https://www.osti.gov/servlets/purl/1267567. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1267567,
title = {Materials Data on SmBi2IO4 by Materials Project},
author = {The Materials Project},
abstractNote = {SmBi2O4I is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Sm3+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. All Sm–O bond lengths are 2.46 Å. Bi3+ is bonded in a 4-coordinate geometry to four equivalent O2- and four equivalent I1- atoms. All Bi–O bond lengths are 2.27 Å. All Bi–I bond lengths are 3.67 Å. O2- is bonded to two equivalent Sm3+ and two equivalent Bi3+ atoms to form a mixture of corner and edge-sharing OSm2Bi2 tetrahedra. I1- is bonded in a distorted body-centered cubic geometry to eight equivalent Bi3+ atoms.},
doi = {10.17188/1267567},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}