Materials Data on Zn3Co2(CN)12 by Materials Project
Abstract
Co2Zn3(CN)12 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Co2+ is bonded in an octahedral geometry to six C+2.17+ atoms. All Co–C bond lengths are 1.87 Å. Zn2+ is bonded in a tetrahedral geometry to four N3- atoms. There is two shorter (1.96 Å) and two longer (1.98 Å) Zn–N bond length. There are two inequivalent C+2.17+ sites. In the first C+2.17+ site, C+2.17+ is bonded in a linear geometry to one Co2+ and one N3- atom. The C–N bond length is 1.17 Å. In the second C+2.17+ site, C+2.17+ is bonded in a linear geometry to one Co2+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C+2.17+ atom. In the second N3- site, N3- is bonded in a distorted linear geometry to one Zn2+ and one C+2.17+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-542858
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Zn3Co2(CN)12; C-Co-N-Zn
- OSTI Identifier:
- 1266763
- DOI:
- https://doi.org/10.17188/1266763
Citation Formats
The Materials Project. Materials Data on Zn3Co2(CN)12 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1266763.
The Materials Project. Materials Data on Zn3Co2(CN)12 by Materials Project. United States. doi:https://doi.org/10.17188/1266763
The Materials Project. 2020.
"Materials Data on Zn3Co2(CN)12 by Materials Project". United States. doi:https://doi.org/10.17188/1266763. https://www.osti.gov/servlets/purl/1266763. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1266763,
title = {Materials Data on Zn3Co2(CN)12 by Materials Project},
author = {The Materials Project},
abstractNote = {Co2Zn3(CN)12 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Co2+ is bonded in an octahedral geometry to six C+2.17+ atoms. All Co–C bond lengths are 1.87 Å. Zn2+ is bonded in a tetrahedral geometry to four N3- atoms. There is two shorter (1.96 Å) and two longer (1.98 Å) Zn–N bond length. There are two inequivalent C+2.17+ sites. In the first C+2.17+ site, C+2.17+ is bonded in a linear geometry to one Co2+ and one N3- atom. The C–N bond length is 1.17 Å. In the second C+2.17+ site, C+2.17+ is bonded in a linear geometry to one Co2+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C+2.17+ atom. In the second N3- site, N3- is bonded in a distorted linear geometry to one Zn2+ and one C+2.17+ atom.},
doi = {10.17188/1266763},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jul 15 00:00:00 EDT 2020},
month = {Wed Jul 15 00:00:00 EDT 2020}
}