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Title: Materials Data on SbPdSe by Materials Project

Abstract

PdSbSe is Spinel-like structured and crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Pd4+ is bonded to three equivalent Sb2- and three equivalent Se2- atoms to form PdSb3Se3 octahedra that share corners with twelve equivalent PdSb3Se3 octahedra, corners with three equivalent SbPd3Se tetrahedra, and corners with three equivalent SeSbPd3 tetrahedra. The corner-sharing octahedra tilt angles range from 63–64°. All Pd–Sb bond lengths are 2.69 Å. All Pd–Se bond lengths are 2.66 Å. Sb2- is bonded to three equivalent Pd4+ and one Se2- atom to form distorted SbPd3Se tetrahedra that share corners with three equivalent PdSb3Se3 octahedra, corners with six equivalent SbPd3Se tetrahedra, and corners with nine equivalent SeSbPd3 tetrahedra. The corner-sharing octahedral tilt angles are 78°. The Sb–Se bond length is 2.69 Å. Se2- is bonded to three equivalent Pd4+ and one Sb2- atom to form SeSbPd3 tetrahedra that share corners with three equivalent PdSb3Se3 octahedra, corners with six equivalent SeSbPd3 tetrahedra, and corners with nine equivalent SbPd3Se tetrahedra. The corner-sharing octahedral tilt angles are 79°.

Authors:
Publication Date:
Other Number(s):
mp-4368
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SbPdSe; Pd-Sb-Se
OSTI Identifier:
1208104
DOI:
https://doi.org/10.17188/1208104

Citation Formats

The Materials Project. Materials Data on SbPdSe by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1208104.
The Materials Project. Materials Data on SbPdSe by Materials Project. United States. doi:https://doi.org/10.17188/1208104
The Materials Project. 2020. "Materials Data on SbPdSe by Materials Project". United States. doi:https://doi.org/10.17188/1208104. https://www.osti.gov/servlets/purl/1208104. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1208104,
title = {Materials Data on SbPdSe by Materials Project},
author = {The Materials Project},
abstractNote = {PdSbSe is Spinel-like structured and crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Pd4+ is bonded to three equivalent Sb2- and three equivalent Se2- atoms to form PdSb3Se3 octahedra that share corners with twelve equivalent PdSb3Se3 octahedra, corners with three equivalent SbPd3Se tetrahedra, and corners with three equivalent SeSbPd3 tetrahedra. The corner-sharing octahedra tilt angles range from 63–64°. All Pd–Sb bond lengths are 2.69 Å. All Pd–Se bond lengths are 2.66 Å. Sb2- is bonded to three equivalent Pd4+ and one Se2- atom to form distorted SbPd3Se tetrahedra that share corners with three equivalent PdSb3Se3 octahedra, corners with six equivalent SbPd3Se tetrahedra, and corners with nine equivalent SeSbPd3 tetrahedra. The corner-sharing octahedral tilt angles are 78°. The Sb–Se bond length is 2.69 Å. Se2- is bonded to three equivalent Pd4+ and one Sb2- atom to form SeSbPd3 tetrahedra that share corners with three equivalent PdSb3Se3 octahedra, corners with six equivalent SeSbPd3 tetrahedra, and corners with nine equivalent SbPd3Se tetrahedra. The corner-sharing octahedral tilt angles are 79°.},
doi = {10.17188/1208104},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}