U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sb2(AuF6)3 by Materials Project
Abstract
Sb2(AuF6)3 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Sb2(AuF6)3 sheet oriented in the (1, 0, 0) direction. there are two inequivalent Au4+ sites. In the first Au4+ site, Au4+ is bonded in a distorted square co-planar geometry to four F1- atoms. There are two shorter (2.15 Å) and two longer (2.17 Å) Au–F bond lengths. In the second Au4+ site, Au4+ is bonded in a distorted rectangular see-saw-like geometry to four F1- atoms. There are a spread of Au–F bond distances ranging from 1.92–2.03 Å. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.89–2.09 Å. There are nine inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to one Au4+ and one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bondedmore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-30109
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sb2(AuF6)3; Au-F-Sb
- OSTI Identifier:
- 1204534
- DOI:
- https://doi.org/10.17188/1204534
Citation Formats
The Materials Project. Materials Data on Sb2(AuF6)3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1204534.
The Materials Project. Materials Data on Sb2(AuF6)3 by Materials Project. United States. doi:https://doi.org/10.17188/1204534
The Materials Project. 2020.
"Materials Data on Sb2(AuF6)3 by Materials Project". United States. doi:https://doi.org/10.17188/1204534. https://www.osti.gov/servlets/purl/1204534. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1204534,
title = {Materials Data on Sb2(AuF6)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Sb2(AuF6)3 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of one Sb2(AuF6)3 sheet oriented in the (1, 0, 0) direction. there are two inequivalent Au4+ sites. In the first Au4+ site, Au4+ is bonded in a distorted square co-planar geometry to four F1- atoms. There are two shorter (2.15 Å) and two longer (2.17 Å) Au–F bond lengths. In the second Au4+ site, Au4+ is bonded in a distorted rectangular see-saw-like geometry to four F1- atoms. There are a spread of Au–F bond distances ranging from 1.92–2.03 Å. Sb3+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.89–2.09 Å. There are nine inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to one Au4+ and one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Au4+ atom. In the seventh F1- site, F1- is bonded in a bent 120 degrees geometry to two Au4+ atoms. In the eighth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Au4+ atoms. In the ninth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1204534},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Apr 29 00:00:00 EDT 2020},
month = {Wed Apr 29 00:00:00 EDT 2020}
}