U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on K2H5F7 by Materials Project
Abstract
K2H5F7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 9-coordinate geometry to nine F1- atoms. There are a spread of K–F bond distances ranging from 2.72–3.20 Å. In the second K1+ site, K1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of K–F bond distances ranging from 2.76–2.80 Å. There are five inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.00 Å) and one longer (1.42 Å) H–F bond length. In the second H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (0.99 Å) and one longer (1.45 Å) H–F bond length. In the third H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.14 Å) and one longer (1.16 Å) H–F bond length. In the fourth H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.05 Å) and one longer (1.30 Å) H–F bond length.more »
- Authors:
- Publication Date:
- Other Number(s):
- mp-29330
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; K2H5F7; F-H-K
- OSTI Identifier:
- 1203688
- DOI:
- https://doi.org/10.17188/1203688
Citation Formats
The Materials Project. Materials Data on K2H5F7 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1203688.
The Materials Project. Materials Data on K2H5F7 by Materials Project. United States. doi:https://doi.org/10.17188/1203688
The Materials Project. 2020.
"Materials Data on K2H5F7 by Materials Project". United States. doi:https://doi.org/10.17188/1203688. https://www.osti.gov/servlets/purl/1203688. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1203688,
title = {Materials Data on K2H5F7 by Materials Project},
author = {The Materials Project},
abstractNote = {K2H5F7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 9-coordinate geometry to nine F1- atoms. There are a spread of K–F bond distances ranging from 2.72–3.20 Å. In the second K1+ site, K1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of K–F bond distances ranging from 2.76–2.80 Å. There are five inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.00 Å) and one longer (1.42 Å) H–F bond length. In the second H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (0.99 Å) and one longer (1.45 Å) H–F bond length. In the third H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.14 Å) and one longer (1.16 Å) H–F bond length. In the fourth H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.05 Å) and one longer (1.30 Å) H–F bond length. In the fifth H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.02 Å) and one longer (1.36 Å) H–F bond length. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted water-like geometry to two equivalent K1+ and two H1+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to three equivalent K1+ and one H1+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to three equivalent K1+ and one H1+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to two equivalent K1+ and one H1+ atom. In the fifth F1- site, F1- is bonded in a distorted water-like geometry to two equivalent K1+ and two H1+ atoms. In the sixth F1- site, F1- is bonded in a single-bond geometry to three K1+ and one H1+ atom. In the seventh F1- site, F1- is bonded in a distorted water-like geometry to two equivalent K1+ and two H1+ atoms.},
doi = {10.17188/1203688},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun May 03 00:00:00 EDT 2020},
month = {Sun May 03 00:00:00 EDT 2020}
}