Materials Data on RbBiF6 by Materials Project
Abstract
RbBiF6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent F1- atoms to form RbF12 cuboctahedra that share corners with six equivalent BiF6 octahedra, edges with six equivalent RbF12 cuboctahedra, and faces with two equivalent BiF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are six shorter (3.05 Å) and six longer (3.29 Å) Rb–F bond lengths. Bi5+ is bonded to six equivalent F1- atoms to form BiF6 octahedra that share corners with six equivalent RbF12 cuboctahedra and faces with two equivalent RbF12 cuboctahedra. All Bi–F bond lengths are 2.05 Å. F1- is bonded in a distorted single-bond geometry to two equivalent Rb1+ and one Bi5+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-27421
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; RbBiF6; Bi-F-Rb
- OSTI Identifier:
- 1201640
- DOI:
- https://doi.org/10.17188/1201640
Citation Formats
The Materials Project. Materials Data on RbBiF6 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1201640.
The Materials Project. Materials Data on RbBiF6 by Materials Project. United States. doi:https://doi.org/10.17188/1201640
The Materials Project. 2020.
"Materials Data on RbBiF6 by Materials Project". United States. doi:https://doi.org/10.17188/1201640. https://www.osti.gov/servlets/purl/1201640. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1201640,
title = {Materials Data on RbBiF6 by Materials Project},
author = {The Materials Project},
abstractNote = {RbBiF6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent F1- atoms to form RbF12 cuboctahedra that share corners with six equivalent BiF6 octahedra, edges with six equivalent RbF12 cuboctahedra, and faces with two equivalent BiF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are six shorter (3.05 Å) and six longer (3.29 Å) Rb–F bond lengths. Bi5+ is bonded to six equivalent F1- atoms to form BiF6 octahedra that share corners with six equivalent RbF12 cuboctahedra and faces with two equivalent RbF12 cuboctahedra. All Bi–F bond lengths are 2.05 Å. F1- is bonded in a distorted single-bond geometry to two equivalent Rb1+ and one Bi5+ atom.},
doi = {10.17188/1201640},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}
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