U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on PuOF by Materials Project
Abstract
PuOF crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Pu3+ is bonded in a body-centered cubic geometry to four equivalent O2- and four equivalent F1- atoms. All Pu–O bond lengths are 2.32 Å. All Pu–F bond lengths are 2.59 Å. O2- is bonded to four equivalent Pu3+ atoms to form distorted OPu4 tetrahedra that share corners with four equivalent OPu4 tetrahedra, corners with twelve equivalent FPu4 tetrahedra, edges with two equivalent FPu4 tetrahedra, and edges with four equivalent OPu4 tetrahedra. F1- is bonded to four equivalent Pu3+ atoms to form distorted FPu4 tetrahedra that share corners with four equivalent FPu4 tetrahedra, corners with twelve equivalent OPu4 tetrahedra, edges with two equivalent OPu4 tetrahedra, and edges with four equivalent FPu4 tetrahedra.
- Authors:
- Publication Date:
- Other Number(s):
- mp-20230
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; PuOF; F-O-Pu
- OSTI Identifier:
- 1195365
- DOI:
- https://doi.org/10.17188/1195365
Citation Formats
The Materials Project. Materials Data on PuOF by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1195365.
The Materials Project. Materials Data on PuOF by Materials Project. United States. doi:https://doi.org/10.17188/1195365
The Materials Project. 2020.
"Materials Data on PuOF by Materials Project". United States. doi:https://doi.org/10.17188/1195365. https://www.osti.gov/servlets/purl/1195365. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1195365,
title = {Materials Data on PuOF by Materials Project},
author = {The Materials Project},
abstractNote = {PuOF crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Pu3+ is bonded in a body-centered cubic geometry to four equivalent O2- and four equivalent F1- atoms. All Pu–O bond lengths are 2.32 Å. All Pu–F bond lengths are 2.59 Å. O2- is bonded to four equivalent Pu3+ atoms to form distorted OPu4 tetrahedra that share corners with four equivalent OPu4 tetrahedra, corners with twelve equivalent FPu4 tetrahedra, edges with two equivalent FPu4 tetrahedra, and edges with four equivalent OPu4 tetrahedra. F1- is bonded to four equivalent Pu3+ atoms to form distorted FPu4 tetrahedra that share corners with four equivalent FPu4 tetrahedra, corners with twelve equivalent OPu4 tetrahedra, edges with two equivalent OPu4 tetrahedra, and edges with four equivalent FPu4 tetrahedra.},
doi = {10.17188/1195365},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}