Materials Data on Eu(MnAs)2 by Materials Project

doi:10.17188/1195272

Title: Materials Data on Eu(MnAs)2 by Materials Project

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Abstract

EuMn2As2 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Eu2+ is bonded to six equivalent As3- atoms to form EuAs6 octahedra that share corners with twelve equivalent MnAs4 tetrahedra, edges with six equivalent EuAs6 octahedra, and edges with six equivalent MnAs4 tetrahedra. All Eu–As bond lengths are 3.04 Å. Mn2+ is bonded to four equivalent As3- atoms to form MnAs4 tetrahedra that share corners with six equivalent EuAs6 octahedra, corners with six equivalent MnAs4 tetrahedra, edges with three equivalent EuAs6 octahedra, and edges with three equivalent MnAs4 tetrahedra. The corner-sharing octahedra tilt angles range from 21–50°. There are one shorter (2.42 Å) and three longer (2.45 Å) Mn–As bond lengths. As3- is bonded in a 7-coordinate geometry to three equivalent Eu2+ and four equivalent Mn2+ atoms.

Authors:: The Materials Project

Publication Date:: Thu Jul 16 00:00:00 EDT 2020

Other Number(s):: mp-20128

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Eu(MnAs)2; As-Eu-Mn

OSTI Identifier:: 1195272

DOI:: https://doi.org/10.17188/1195272

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                    The Materials Project. Materials Data on Eu(MnAs)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1195272.

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                    The Materials Project. Materials Data on Eu(MnAs)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1195272

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                    The Materials Project. 2020.  
"Materials Data on Eu(MnAs)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1195272.  https://www.osti.gov/servlets/purl/1195272. Pub date:Thu Jul 16 00:00:00 EDT 2020

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@article{osti_1195272,

  title        = {Materials Data on Eu(MnAs)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {EuMn2As2 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Eu2+ is bonded to six equivalent As3- atoms to form EuAs6 octahedra that share corners with twelve equivalent MnAs4 tetrahedra, edges with six equivalent EuAs6 octahedra, and edges with six equivalent MnAs4 tetrahedra. All Eu–As bond lengths are 3.04 Å. Mn2+ is bonded to four equivalent As3- atoms to form MnAs4 tetrahedra that share corners with six equivalent EuAs6 octahedra, corners with six equivalent MnAs4 tetrahedra, edges with three equivalent EuAs6 octahedra, and edges with three equivalent MnAs4 tetrahedra. The corner-sharing octahedra tilt angles range from 21–50°. There are one shorter (2.42 Å) and three longer (2.45 Å) Mn–As bond lengths. As3- is bonded in a 7-coordinate geometry to three equivalent Eu2+ and four equivalent Mn2+ atoms.},

  doi          = {10.17188/1195272},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Jul 16 00:00:00 EDT 2020},

  month        = {Thu Jul 16 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1195272

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