U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sr2Mn3(SbO)2 by Materials Project
Abstract
Sr2Mn3(SbO)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sr2+ is bonded in a 4-coordinate geometry to four equivalent Sb3- and four equivalent O2- atoms. All Sr–Sb bond lengths are 3.51 Å. All Sr–O bond lengths are 2.71 Å. There are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a square co-planar geometry to two equivalent Sb3- and four equivalent O2- atoms. Both Mn–Sb bond lengths are 3.31 Å. All Mn–O bond lengths are 2.17 Å. In the second Mn2+ site, Mn2+ is bonded to four equivalent Sb3- atoms to form a mixture of corner and edge-sharing MnSb4 tetrahedra. All Mn–Sb bond lengths are 2.84 Å. Sb3- is bonded in a 9-coordinate geometry to four equivalent Sr2+ and five Mn2+ atoms. O2- is bonded to four equivalent Sr2+ and two equivalent Mn2+ atoms to form a mixture of corner, edge, and face-sharing OSr4Mn2 octahedra. The corner-sharing octahedral tilt angles are 0°.
- Authors:
- Publication Date:
- Other Number(s):
- mp-19246
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sr2Mn3(SbO)2; Mn-O-Sb-Sr
- OSTI Identifier:
- 1194104
- DOI:
- https://doi.org/10.17188/1194104
Citation Formats
The Materials Project. Materials Data on Sr2Mn3(SbO)2 by Materials Project. United States: N. p., 2014.
Web. doi:10.17188/1194104.
The Materials Project. Materials Data on Sr2Mn3(SbO)2 by Materials Project. United States. doi:https://doi.org/10.17188/1194104
The Materials Project. 2014.
"Materials Data on Sr2Mn3(SbO)2 by Materials Project". United States. doi:https://doi.org/10.17188/1194104. https://www.osti.gov/servlets/purl/1194104. Pub date:Sat Feb 15 00:00:00 EST 2014
@article{osti_1194104,
title = {Materials Data on Sr2Mn3(SbO)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Sr2Mn3(SbO)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sr2+ is bonded in a 4-coordinate geometry to four equivalent Sb3- and four equivalent O2- atoms. All Sr–Sb bond lengths are 3.51 Å. All Sr–O bond lengths are 2.71 Å. There are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded in a square co-planar geometry to two equivalent Sb3- and four equivalent O2- atoms. Both Mn–Sb bond lengths are 3.31 Å. All Mn–O bond lengths are 2.17 Å. In the second Mn2+ site, Mn2+ is bonded to four equivalent Sb3- atoms to form a mixture of corner and edge-sharing MnSb4 tetrahedra. All Mn–Sb bond lengths are 2.84 Å. Sb3- is bonded in a 9-coordinate geometry to four equivalent Sr2+ and five Mn2+ atoms. O2- is bonded to four equivalent Sr2+ and two equivalent Mn2+ atoms to form a mixture of corner, edge, and face-sharing OSr4Mn2 octahedra. The corner-sharing octahedral tilt angles are 0°.},
doi = {10.17188/1194104},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Feb 15 00:00:00 EST 2014},
month = {Sat Feb 15 00:00:00 EST 2014}
}