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Title: ARM: AOS: Sulfur Dioxide Analyzer

AOS: Sulfur Dioxide Analyzer
Authors:
Publication Date:
DOE Contract Number:
DE-AC05-00OR22725
Product Type:
Dataset
Research Org(s):
Atmospheric Radiation Measurement (ARM) Archive, Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (US)
Sponsoring Org:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
Subject:
54 Environmental Sciences; Atmospheric moisture; Black carbon concentration; Carbon dioxide (CO2) concentration; Carbon monoxide (CO) Concentration; Inorganic chemical composition; Nitrogen; Ozone; Ozone Concentration; Sulfur Dioxide (SO2) Concentration; Trace gas concentration
OSTI Identifier:
1095586
  1. ARM focuses on obtaining continuous measurements—supplemented by field campaigns—and providing data products that promote the advancement of climate models. ARM data include routine data products, value-added products (VAPs), field campaign data, complementary external data products from collaborating programs, and data contributed by ARM principal investigators for use by the scientific community. Data quality reports, graphical displays of data availability/quality, and data plots are also available from the ARM Data Center. Serving users worldwide, the ARM Data Center collects and archives approximately 20 terabytes of data per month. Datastreams are generally available for download within 48 hours.
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  1. The heart of the AOS CO2 Airborne Rack Mounted Analyzer System is the AOS Manifold. The AOS Manifold is a nickel coated aluminum analyzer and gas processor designed around two identical nickel-plated gas cells, one for reference gas and one for sample gas. The samplemore » and reference cells are uniquely designed to provide optimal flushing efficiency. These cells are situated between a black-body radiation source and a photo-diode detection system. The AOS manifold also houses flow meters, pressure sensors and control valves. The exhaust from the analyzer flows into a buffer volume which allows for precise pressure control of the analyzer. The final piece of the analyzer is the demodulator board which is used to convert the DC signal generated by the analyzer into an AC response. The resulting output from the demodulator board is an averaged count of CO2 over a specified hertz cycle reported in volts and a corresponding temperature reading. The system computer is responsible for the input of commands and therefore works to control the unit functions such as flow rate, pressure, and valve control.The remainder of the system consists of compressors, reference gases, air drier, electrical cables, and the necessary connecting plumbing to provide a dry sample air stream and reference air streams to the AOS manifold. « less
  2. The heart of the AOS CO2 Airborne Rack Mounted Analyzer System is the AOS Manifold. The AOS Manifold is a nickel coated aluminum analyzer and gas processor designed around two identical nickel-plated gas cells, one for reference gas and one for sample gas. The samplemore » and reference cells are uniquely designed to provide optimal flushing efficiency. These cells are situated between a black-body radiation source and a photo-diode detection system. The AOS manifold also houses flow meters, pressure sensors and control valves. The exhaust from the analyzer flows into a buffer volume which allows for precise pressure control of the analyzer. The final piece of the analyzer is the demodulator board which is used to convert the DC signal generated by the analyzer into an AC response. The resulting output from the demodulator board is an averaged count of CO2 over a specified hertz cycle reported in volts and a corresponding temperature reading. The system computer is responsible for the input of commands and therefore works to control the unit functions such as flow rate, pressure, and valve control.The remainder of the system consists of compressors, reference gases, air drier, electrical cables, and the necessary connecting plumbing to provide a dry sample air stream and reference air streams to the AOS manifold. « less
  3. Determinations of atmospheric CO2 mixing ratios are made using a Siemens Ultramat-3 nondispersive infrared (NDIR) gas analyzer. The NDIR CO2 analyzer is connected via a gas manifold consisting of stainless steel tubing and computer-controlled solenoid switches to 12 gas cylinders and 2 sample air lines.more » The NDIR analyzer compares ambient air CO2 mixing ratios relative to known CO2 mixing ratios in tanks of compressed reference gases. The analyzer operates in a differential mode, with a "zero" reference gas of CO2 mixing ratio 20 to 30 parts per million (ppm) below ambient air CO2 levels flowing continuously through one cell of the analyzer at ~10 mL/min. When atmospheric CO2 is measured, a diaphragm pump pulls air through a sampling line at ~5 L/min. A small fraction of this (180 mL/min) is dried cryogenically to a temperature of approximately ¬70° Celsius and passed through the sample cell of the CO2 analyzer. Both the "zero" and sample gas are exhausted into the observatory building. « less
  4. This data set presents measured values of plant diameter and height, biomass of plant components, and nutrient (carbon, nitrogen, phosphorus, sulfur, potassium, calcium, magnesium, boron, copper, iron, manganese, and zinc) concentrations from a study of the effects of carbon dioxide and nitrogen fertilization on ponderosamore » pine (Pinus ponderosa Dougl. ex Laws.) conducted in open-top chambers in Placerville, California, from 1991 through 1996. This data set contains values from 1991 through 1993. « less
  5. Continuous atmospheric CO2 measurements have been carried out at Mt. Cimone since 1979. Since December 1988, air samples have also been collected approximately once per week in a pair of 2-L, electropolished, stainless steel cylindrical flasks. From 1979 until December 1988, a Hartmann and Braunmore » URAS-2T NDIR gas analyzer was used for CO2 determinations. Currently, CO2 determinations are made through the use of a Siemens Ultramat-5E NDIR gas analyzer. Water vapor is eliminated by passing the air through a U-tube placed in an alcohol bath at -600°C. Calibration of the Ultramat-5E is accomplished by using two CO2-in-air working standard gases. These working standard gas concentrations are checked 10 days apart against three CO2-in-air mixtures that serve as secondary standards. The secondary standards are checked every 6 months against five other CO2-in-air primary standards. Hourly CO2 values are routinely plotted together with wind data. Anomalous concentrations and those affected by instrument failures or local sources are rejected. Atmospheric CO2 concentrations from Mt. Cimone are reported in the 1993 WMO/Scripps mole fraction scale. For further details on the measurement apparatus and sampling techniques used at Mt. Cimone, see Cundari et al. (1990). « less