An N-Heterocyclic Carbene as a Bidentate Hemilabile Ligand: A Synchrotron X-ray Diffraction and Density Functional Theory Study
Journal Article
·
· Chemical Communications, 2003(14):1670-1671
The N?heterocyclic carbene ligand IMes was shown by synchrotron crystallography and DFT computations to adopt a hemilabile bidentate coordination mode in CpM(CO)2(IMes)+B(C6F5)4- (M = Mo, W), with a C=C bond of one mesityl weakly coordinated to the metal
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 993677
- Report Number(s):
- PNNL-SA-38943; KC0302010; TRN: US1008107
- Journal Information:
- Chemical Communications, 2003(14):1670-1671, Vol. 2003, Issue 14
- Country of Publication:
- United States
- Language:
- English
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