Recent Advances in Pt Monolayer Electrocatalysts for Oxygen Reduction Reaction: Scale-up Synthesis, Structure, and Activity of Pt Shells on Pd Cores
- Brookhaven National Laboratory (BNL)
- Toyota Motor Corp.
- University of Delaware
- ORNL
- Hitachi High Technologies America
We have established a scale-up synthesis method to produce gram-quantities of Pt monolayer electrocatalysts. The core-shell structure of the Pt/Pd/C electrocatalyst has been verified using the HAADF-STEM Z-contrast images, STEM/EELS, and STEM/EDS line profile analysis. The atomic structure of this electrocatalyst and formation of a Pt monolayer on Pd nanoparticle surfaces were examined using in situ EXAFS. The Pt mass activity of the Pt/Pd/C electrocatalyst for ORR is considerably higher than that of commercial Pt/C electrocatalysts. The results with Pt monolayer electrocatalysts may significantly impact science of electrocatalysis and fuel-cell technology, as they have demonstrated an exceptionally effective way of using Pt that can resolve problems of other approaches, including electrocatalysts inadequate activity and high Pt content.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Shared Research Equipment Collaborative Research Center
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC05-00OR22725
- OSTI ID:
- 989151
- Journal Information:
- Electrochimica Acta, Vol. 55, Issue 8; ISSN 0013-4686
- Country of Publication:
- United States
- Language:
- English
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