Electrolytic orthoborate salts for lithium batteries

Angell, Charles Austen; Xu, Wu

Electrolytic orthoborate salts for lithium batteries

Patent · 05 May 2009

OSTI ID:988160

Angell, Charles Austen ^[1]; Xu, Wu ^[2]

Mesa, AZ
Tempe, AZ

Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

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Research Organization:: Arizona State University (Tempe, AZ)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG03-95ER45541; FG03-93ER14378

Assignee:: Arizona Board of Regents for and on behalf of Arizona State University (Tempe, AZ)

Patent Number(s):: 7,527,899

Application Number:: 10/311,605

OSTI ID:: 988160

Country of Publication:: United States

Language:: English

References (34)

Polyanionic electrolytes with high alkali ion conductivity Sun, Xiao-Guang; Xu, Wu; Zhang, Sheng-Shui Journal of Physics: Condensed Matter, Vol. 13, Issue 36 https://doi.org/10.1088/0953-8984/13/36/301	journal	August 2001
Borkomplexe mit Dicarbonsäuren: Bis(oxalato)borate und Bis(malonato)borate/Boron Complexes with Dicarboxylic Acids: Bis(oxalato)borates and Bis(malonato)borates Bessler, Eberhard; Weidlein, Johann Zeitschrift für Naturforschung B, Vol. 37, Issue 8 https://doi.org/10.1515/znb-1982-0813	journal	August 1982
Molecular and anionic polymer and oligomer systems with microdecoupled conductivities Zhang, Shengshui; Chang, Zheng; Xu, Kang Electrochimica Acta, Vol. 45, Issue 8-9 https://doi.org/10.1016/S0013-4686(99)00385-0	journal	January 2000
Variations on the salt-polymer electrolyte theme for flexible solid electrolytes Angell, C. A.; Xu, K.; Zhang, S-S. Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00088-4	journal	July 1996
Aluminosilicate/Poly(ethylene glycol) Copolymers: A New Class of Polyelectrolytes Rawsky, Glenn C.; Fujinami, Tatsuo; Shriver, D. F. Chemistry of Materials, Vol. 6, Issue 12 https://doi.org/10.1021/cm00048a003	journal	December 1994
Li-conducting ionic rubbers for lithium battery and other applications Austenangell, C.; Fan, J.; Liu, C. Solid State Ionics, Vol. 69, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90422-7	journal	August 1994
LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation Xu, Kang; Zhang, Shengshui; Jow, T. Richard Electrochemical and Solid-State Letters, Vol. 5, Issue 1 https://doi.org/10.1149/1.1426042	journal	January 2002
The history of polymer electrolytes Armand, M. Solid State Ionics, Vol. 69, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90419-7	journal	August 1994
Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions Sloop, S. E.; Pugh, J. K.; Wang, S. Electrochemical and Solid-State Letters, Vol. 4, Issue 4 https://doi.org/10.1149/1.1353158	journal	January 2001
Fast ion motion in glassy and amorphous materials Angell, C. Solid State Ionics, Vol. 9-10 https://doi.org/10.1016/0167-2738(83)90206-0	journal	December 1983
Siloxyaluminate Polymers with High Li ⁺ Ion Conductivity Fujinami, Tatsuo; Tokimune, Akira; Mehta, Mary Anne Chemistry of Materials, Vol. 9, Issue 10 https://doi.org/10.1021/cm970399z	journal	October 1997
The use of boroxine rings for the development of high performance polymer electrolytes Anne Mehta, Mary; Fujinami, Tatsuo; Inoue, Satoshi Electrochimica Acta, Vol. 45, Issue 8-9 https://doi.org/10.1016/S0013-4686(99)00378-3	journal	January 2000
Corrosion of aluminum at high voltages in non-aqueous electrolytes containing perfluoroalkylsulfonyl imides; new lithium salts for lithium-ion cells Krause, Larry J.; Lamanna, William; Summerfield, John Journal of Power Sources, Vol. 68, Issue 2 https://doi.org/10.1016/S0378-7753(97)02517-2	journal	October 1997
Non-Crystallizing Molten Salt and Ionic Rubber Electrolytes with Wide Electrochemical Windows Xu, K.; Angell, C. A. MRS Proceedings, Vol. 369 https://doi.org/10.1557/PROC-369-505	journal	January 1994
Eine einfache Synthese von Trichloromethyltrimethylsilan und Carbonsäure-trimethylsilylestern Hergott, Hans Herbert; Simchen, Gerhard Synthesis, Vol. 1980, Issue 08 https://doi.org/10.1055/s-1980-29144	journal	January 1980
Polyether/salt hybrid (IV). Effect of benzenesulfonate group(s) and PEO molecular weight on the bulk ionic conductivity Ito, Kaori; Tominaga, Yoichi; Ohno, Hiroyuki Electrochimica Acta, Vol. 42, Issue 10 https://doi.org/10.1016/S0013-4686(96)00317-9	journal	January 1997
Molten salt type polymer electrolytes Ohno, Hiroyuki Electrochimica Acta, Vol. 46, Issue 10-11 https://doi.org/10.1016/S0013-4686(00)00733-7	journal	March 2001
A Fusible Orthoborate Lithium Salt with High Conductivity in Solutions Xu, Wu Electrochemical and Solid-State Letters, Vol. 3, Issue 8 https://doi.org/10.1149/1.1391150	journal	January 1999
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes Barthel, J. Journal of The Electrochemical Society, Vol. 143, Issue 11 https://doi.org/10.1149/1.1837254	journal	January 1996
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes. V. Synthesis and Properties of Lithium Bis[2,3-pyridinediolato(2−)-O,Oʹ]borate Barthel, J.; Schmid, A.; Gores, H. J. Journal of The Electrochemical Society, Vol. 147, Issue 1 https://doi.org/10.1149/1.1393138	journal	January 2000
Effect of terminal groups on the ionic conductivity of α,ω-dicharged poly(ethylene oxide) oligomers Ito, Kaori; Nishina, Naoko; Tominaga, Yoichi Solid State Ionics, Vol. 86-88 https://doi.org/10.1016/0167-2738(96)00140-3	journal	July 1996
LiBOB and Its Derivatives: Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions [Electrochem. Solid-State Lett., 4, E1 (2001)] Xu, W.; Angell, C. A. Electrochemical and Solid-State Letters, Vol. 4, Issue 3 https://doi.org/10.1149/1.1347858	journal	January 2001
The determination of transference numbers in solid polymer electrolytes using the Hittorf method Bruce, Peter G.; Hardgrave, Martin T.; Vincent, Colin A. Solid State Ionics, Vol. 53-56 https://doi.org/10.1016/0167-2738(92)90295-Z	journal	July 1992
Rubbery solid electrolytes with dominant cationic transport and high ambient conductivity Angell, C. A.; Liu, C.; Sanchez, E. Nature, Vol. 362, Issue 6416 https://doi.org/10.1038/362137a0	journal	March 1993
Novel Polyanionic Solid Electrolytes with Weak Coulomb Traps and Controllable Caps and Spacers Xu, Wu; Williams, Michael D.; Angell, C. Austen Chemistry of Materials, Vol. 14, Issue 1 https://doi.org/10.1021/cm010699n	journal	January 2002
Preparation and characterization of novel “polyMOB” polyanionic solid electrolytes with weak coulomb traps Xu, W. Solid State Ionics, Vol. 147, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00032-2	journal	April 2002
Ionic Conductivity of Molten Salts Formed by Polyether/salt Hybrids Ohno, Hiroyuki; Nakai, Yoshikazu; Ito, Kaori Chemistry Letters, Vol. 27, Issue 1 https://doi.org/10.1246/cl.1998.15	journal	January 1998
Lithium/Polyaniline Secondary Battery Composed of Transport-Number-Adjusted Aluminate Solid Polymer Electrolytes Onishi, Ken; Matsumoto, Michiko; Shigehara, Kiyotaka Journal of The Electrochemical Society, Vol. 147, Issue 6 https://doi.org/10.1149/1.1393482	journal	January 2000
Thioaluminate Polymer Complexes as Single-Ionic Solid Electrolytes Onishi, Ken; Matsumoto, Michiko; Shigehara, Kiyotaka Chemistry of Materials, Vol. 10, Issue 3 https://doi.org/10.1021/cm970717u	journal	March 1998
Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes Xu, K.; Angell, C. A. Electrochimica Acta, Vol. 40, Issue 13-14 https://doi.org/10.1016/0013-4686(95)00203-Q	journal	October 1995
Ionic Liquids of Chelated Orthoborates as Model Ionic Glassformers Xu, Wu; Wang, Li-Min; Nieman, Ronald A. The Journal of Physical Chemistry B, Vol. 107, Issue 42 https://doi.org/10.1021/jp034548e	journal	October 2003
LiMOB, an Unsymmetrical Nonaromatic Orthoborate Salt for Nonaqueous Solution Electrochemical Applications Xu, Wu; Shusterman, Alan J.; Marzke, Robert Journal of The Electrochemical Society, Vol. 151, Issue 4 https://doi.org/10.1149/1.1651528	journal	January 2004
Solvent-Free Electrolytes with Aqueous Solution-Like Conductivities Xu, W. Science, Vol. 302, Issue 5644 https://doi.org/10.1126/science.1090287	journal	October 2003
Boroxine ring containing polymer electrolytes Mehta, Mary Anne; Fujinami, Tatsuo; Inoue, Takayoshi Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(99)00151-2	journal	September 1999

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