skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Conductive polymeric compositions for lithium batteries

Patent ·
OSTI ID:986364

Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

Research Organization:
Arizona State Univ., Tempe, AZ (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG03-95ER45541
Assignee:
Arizona Board of Regents for and on behalf of Arizona State University (Scottsdale, AZ)
Patent Number(s):
7,504,473
Application Number:
10/311,643
OSTI ID:
986364
Country of Publication:
United States
Language:
English

References (35)

LiMOB, an Unsymmetrical Nonaromatic Orthoborate Salt for Nonaqueous Solution Electrochemical Applications journal January 2004
Rubbery solid electrolytes with dominant cationic transport and high ambient conductivity journal March 1993
Lithium/Polyaniline Secondary Battery Composed of Transport-Number-Adjusted Aluminate Solid Polymer Electrolytes journal January 2000
Molten salt type polymer electrolytes journal March 2001
Ionic Conductivity of Molten Salts Formed by Polyether/salt Hybrids journal January 1998
Ionic Liquids of Chelated Orthoborates as Model Ionic Glassformers journal October 2003
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes journal January 1996
The determination of transference numbers in solid polymer electrolytes using the Hittorf method journal July 1992
Effect of terminal groups on the ionic conductivity of α,ω-dicharged poly(ethylene oxide) oligomers journal July 1996
Aluminosilicate/Poly(ethylene glycol) Copolymers: A New Class of Polyelectrolytes journal December 1994
Corrosion of aluminum at high voltages in non-aqueous electrolytes containing perfluoroalkylsulfonyl imides; new lithium salts for lithium-ion cells journal October 1997
Fast ion motion in glassy and amorphous materials journal December 1983
Molecular and anionic polymer and oligomer systems with microdecoupled conductivities journal January 2000
LiBOB and Its Derivatives: Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions [Electrochem. Solid-State Lett., 4, E1 (2001)] journal January 2001
Preparation and characterization of novel “polyMOB” polyanionic solid electrolytes with weak coulomb traps journal April 2002
The history of polymer electrolytes journal August 1994
LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation journal January 2002
A Fusible Orthoborate Lithium Salt with High Conductivity in Solutions journal January 1999
Variations on the salt-polymer electrolyte theme for flexible solid electrolytes journal July 1996
Boroxine ring containing polymer electrolytes journal September 1999
Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions journal January 2001
Li-conducting ionic rubbers for lithium battery and other applications journal August 1994
Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions journal January 2001
Eine einfache Synthese von Trichloromethyltrimethylsilan und Carbonsäure-trimethylsilylestern journal January 1980
Borkomplexe mit Dicarbonsäuren: Bis(oxalato)borate und Bis(malonato)borate/Boron Complexes with Dicarboxylic Acids: Bis(oxalato)borates and Bis(malonato)borates journal August 1982
Thioaluminate Polymer Complexes as Single-Ionic Solid Electrolytes journal March 1998
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes. V. Synthesis and Properties of Lithium Bis[2,3-pyridinediolato(2−)-O,Oʹ]borate journal January 2000
Novel Polyanionic Solid Electrolytes with Weak Coulomb Traps and Controllable Caps and Spacers journal January 2002
Siloxyaluminate Polymers with High Li + Ion Conductivity journal October 1997
Solvent-Free Electrolytes with Aqueous Solution-Like Conductivities journal October 2003
The use of boroxine rings for the development of high performance polymer electrolytes journal January 2000
Non-Crystallizing Molten Salt and Ionic Rubber Electrolytes with Wide Electrochemical Windows journal January 1994
Synthesis and characterization of lithium sulfonates as components of molten salt electrolytes journal October 1995
Polyanionic electrolytes with high alkali ion conductivity journal August 2001
Polyether/salt hybrid (IV). Effect of benzenesulfonate group(s) and PEO molecular weight on the bulk ionic conductivity journal January 1997

Similar Records

Electrolytic orthoborate salts for lithium batteries
Patent · Tue May 05 00:00:00 EDT 2009 · OSTI ID:986364

Electrolytic orthoborate salts for lithium batteries
Patent · Tue Jan 01 00:00:00 EST 2008 · OSTI ID:986364

Solid polymeric electrolytes for lithium batteries
Patent · Tue Mar 14 00:00:00 EST 2006 · OSTI ID:986364

Related Subjects