Nickel-titanium-phosphate cathodes
Patent
·
OSTI ID:985709
- Westmont, IL
- Downers Grove, IL
Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-31109-ENG-38;
- Assignee:
- UChicago Argonne LLC (Chicago, IL)
- Patent Number(s):
- 7,465,520
- Application Number:
- 10/858,806
- OSTI ID:
- 985709
- Country of Publication:
- United States
- Language:
- English
Preparation and structural characterization of two new titanium phosphates NaCaTi(PO) AND NiTiOPO
|
journal | January 1998 |
Ab initio determination and Rietveld refinement of the crystal structure of Ni 0.50 TiO ( PO 4 )
|
journal | March 1999 |
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