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Liquid-liquid interfacial nanoparticle assemblies

Patent ·
OSTI ID:985539
Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.
Research Organization:
University of Massachusetts (Amherst, MA)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-96ER45612;
Assignee:
University of Massachusetts (Amherst, MA)
Patent Number(s):
7,470,840
Application Number:
10/753,868
OSTI ID:
985539
Country of Publication:
United States
Language:
English

References (10)

Drawing Small Cations into Highly Charged Porous Nanocontainers Reveals “Water” Assembly and Related Interaction Problems journal May 2003
Self-assembly of colloidal crystals journal February 1998
Reversible Voltage-Induced Assembly of Au Nanoparticles at Liquid|Liquid Interfaces journal January 2004
Temperature-Programmed Desorption Studies of n -Alkane Derivatives on Graphite:  Desorption Energetics and the Influence of Functional Groups on Adsorbate Self-Assembly journal April 2003
Electric-field-induced capillary attraction between like-charged particles at liquid interfaces journal November 2002
Entropically driven self–assembly and interaction in suspension
  • Yodh, A. G.; Lin, K.; Crocker, J. C.
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 359, Issue 1782 https://doi.org/10.1098/rsta.2000.0810
journal May 2001
Hard Spheres in Vesicles: Curvature-Induced Forces and Particle-Induced Curvature journal January 1998
Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles journal November 2002
Nanoparticle Assembly and Transport at Liquid-Liquid Interfaces journal January 2003
Self-Assembly of Mesoscale Objects into Ordered Two-Dimensional Arrays journal April 1997

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