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Title: Structures of polynuclear Th(IV) hydrolysis products.

Abstract

The hydrolysis chemistry of the tetravalent actinides is discussed based on recent studies with thorium. The coupling of high energy x-ray scattering and single crystal diffraction has provided insight into the structures of the polynuclear complexes formed by hydrolytic reactions of the tetravalent actinides. The success of these experiments with thorium presents many opportunities for the elucidation of the structures and thermodynamic quantities describing the dissolved polynuclear complexes of the heavier actinides.

Authors:
; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
971946
Report Number(s):
ANL/CHM/CP-58250
TRN: US201005%%71
DOE Contract Number:  
DE-AC02-06CH11357
Resource Type:
Conference
Resource Relation:
Conference: 2006 Materials Research Society Fall Meeting; Nov. 27, 2006 - Dec. 1, 2006; Boston, MA
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; ACTINIDES; CHEMISTRY; DIFFRACTION; HYDROLYSIS; MONOCRYSTALS; SCATTERING; THERMODYNAMICS; THORIUM

Citation Formats

Wilson, R. E., Skanthakumar, S., Soderholm, L., and Chemistry. Structures of polynuclear Th(IV) hydrolysis products.. United States: N. p., 2007. Web.
Wilson, R. E., Skanthakumar, S., Soderholm, L., & Chemistry. Structures of polynuclear Th(IV) hydrolysis products.. United States.
Wilson, R. E., Skanthakumar, S., Soderholm, L., and Chemistry. Mon . "Structures of polynuclear Th(IV) hydrolysis products.". United States. doi:.
@article{osti_971946,
title = {Structures of polynuclear Th(IV) hydrolysis products.},
author = {Wilson, R. E. and Skanthakumar, S. and Soderholm, L. and Chemistry},
abstractNote = {The hydrolysis chemistry of the tetravalent actinides is discussed based on recent studies with thorium. The coupling of high energy x-ray scattering and single crystal diffraction has provided insight into the structures of the polynuclear complexes formed by hydrolytic reactions of the tetravalent actinides. The success of these experiments with thorium presents many opportunities for the elucidation of the structures and thermodynamic quantities describing the dissolved polynuclear complexes of the heavier actinides.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}

Conference:
Other availability
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