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Title: Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.

Abstract

Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH{sub 3}){sub 2}NH{sub 2}]M(HCOO){sub 3}, where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
NSF-DMR
OSTI Identifier:
966339
Report Number(s):
ANL/XSD/JA-65104
Journal ID: ISSN 0002-7863; JACSAT; TRN: US200921%%368
DOE Contract Number:  
DE-AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
J. Am. Chem. Soc.
Additional Journal Information:
Journal Volume: 131; Journal Issue: 38 ; Sep. 30, 2009; Journal ID: ISSN 0002-7863
Country of Publication:
United States
Language:
ENGLISH
Subject:
08 HYDROGEN; ARCHITECTURE; BONDING; CATIONS; HYDROGEN; PEROVSKITE

Citation Formats

Jain, P, Ramachandran, V, Clark, R J, Zhou, H D, Toby, B H, Dalal, N, Kroto, H W, Cheetham, A K, X-Ray Science Division, Florida State Univ., and Univ. of Cambridge. Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.. United States: N. p., 2009. Web. doi:10.1021/ja904156s.
Jain, P, Ramachandran, V, Clark, R J, Zhou, H D, Toby, B H, Dalal, N, Kroto, H W, Cheetham, A K, X-Ray Science Division, Florida State Univ., & Univ. of Cambridge. Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.. United States. https://doi.org/10.1021/ja904156s
Jain, P, Ramachandran, V, Clark, R J, Zhou, H D, Toby, B H, Dalal, N, Kroto, H W, Cheetham, A K, X-Ray Science Division, Florida State Univ., and Univ. of Cambridge. Wed . "Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.". United States. https://doi.org/10.1021/ja904156s.
@article{osti_966339,
title = {Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.},
author = {Jain, P and Ramachandran, V and Clark, R J and Zhou, H D and Toby, B H and Dalal, N and Kroto, H W and Cheetham, A K and X-Ray Science Division and Florida State Univ. and Univ. of Cambridge},
abstractNote = {Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH{sub 3}){sub 2}NH{sub 2}]M(HCOO){sub 3}, where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.},
doi = {10.1021/ja904156s},
url = {https://www.osti.gov/biblio/966339}, journal = {J. Am. Chem. Soc.},
issn = {0002-7863},
number = 38 ; Sep. 30, 2009,
volume = 131,
place = {United States},
year = {2009},
month = {9}
}