Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.

doi:https://doi.org/10.1021/ja904156s

Title: Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.

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Abstract

Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH{sub 3}){sub 2}NH{sub 2}]M(HCOO){sub 3}, where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.

Authors:: Jain, P; Ramachandran, V; Clark, R J; Zhou, H D; Toby, B H; Dalal, N; Kroto, H W; Cheetham, A K

Publication Date:: 2009-09-30

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: NSF-DMR

OSTI Identifier:: 966339

Report Number(s):: ANL/XSD/JA-65104
Journal ID: ISSN 0002-7863; JACSAT; TRN: US200921%%368

DOE Contract Number:: DE-AC02-06CH11357

Resource Type:: Journal Article

Journal Name:: J. Am. Chem. Soc.

Additional Journal Information:: Journal Volume: 131; Journal Issue: 38 ; Sep. 30, 2009; Journal ID: ISSN 0002-7863

Country of Publication:: United States

Language:: ENGLISH

Subject:: 08 HYDROGEN; ARCHITECTURE; BONDING; CATIONS; HYDROGEN; PEROVSKITE

Citation Formats


                    Jain, P, Ramachandran, V, Clark, R J, Zhou, H D, Toby, B H, Dalal, N, Kroto, H W, Cheetham, A K, X-Ray Science Division, Florida State Univ., and Univ. of Cambridge. Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture..  United States: N. p., 2009. 
        Web.  doi:10.1021/ja904156s.

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                    Jain, P, Ramachandran, V, Clark, R J, Zhou, H D, Toby, B H, Dalal, N, Kroto, H W, Cheetham, A K, X-Ray Science Division, Florida State Univ., & Univ. of Cambridge. Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture..  United States.  https://doi.org/10.1021/ja904156s

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                    Jain, P, Ramachandran, V, Clark, R J, Zhou, H D, Toby, B H, Dalal, N, Kroto, H W, Cheetham, A K, X-Ray Science Division, Florida State Univ., and Univ. of Cambridge. Wed .  
        "Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.".  United States.  https://doi.org/10.1021/ja904156s.

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@article{osti_966339,

  title        = {Multiferroic behavior associated with an order-disorder hydrogen bonding transition in metal-organic frameworks (MOFs) with the perovskite ABX{sub 3} arhitecture.},

  author       = {Jain, P and Ramachandran, V and Clark, R J and Zhou, H D and Toby, B H and Dalal, N and Kroto, H W and Cheetham, A K and X-Ray Science Division and Florida State Univ. and Univ. of Cambridge},

  abstractNote = {Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH{sub 3}){sub 2}NH{sub 2}]M(HCOO){sub 3}, where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.},

  doi          = {10.1021/ja904156s},

  url          = {https://www.osti.gov/biblio/966339},
  journal      = {J. Am. Chem. Soc.},

  issn         = {0002-7863},

  number       = 38 ; Sep. 30, 2009,

  volume       = 131,

  place        = {United States},

  year         = {2009},

  month        = {9}

}

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