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Title: Global Failure Criteria for Positive/Electrolyte/Negative Structure of Planar Solid Oxide Fuel Cell

Abstract

Due to mismatch of the coefficients of thermal expansion of various layers in the positive/electrolyte/negative (PEN) structures of solid oxide fuel cells (SOFC), thermal stresses and warpage on the PEN are unavoidable due to the temperature changes from the stress-free sintering temperature to room temperature during the PEN manufacturing process. In the meantime, additional mechanical stresses will also be created by mechanical flattening during the stack assembly process. In order to ensure the structural integrity of the cell and stack of SOFC, it is necessary to develop failure criteria for SOFC PEN structures based on the initial flaws occurred during cell sintering and stack assembly. In this paper, the global relationship between the critical energy release rate and critical curvature and maximum displacement of the warped cells caused by the temperature changes as well as mechanical flattening process is established so that possible failure of SOFC PEN structures may be predicted deterministically by the measurement of the curvature and displacement of the warped cells.

Authors:
; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
964221
Report Number(s):
PNNL-SA-65190
AA2530000
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Power Sources, 192(2):486-493
Country of Publication:
United States
Language:
English
Subject:
SOFC PEN, ceramics, fracture mechanism, global fracture criteria, energy release rate, critical curvature

Citation Formats

Liu, Wenning N., Sun, Xin, Khaleel, Mohammad A., and Qu, Jianmin. Global Failure Criteria for Positive/Electrolyte/Negative Structure of Planar Solid Oxide Fuel Cell. United States: N. p., 2009. Web. doi:10.1016/j.jpowsour.2009.03.012.
Liu, Wenning N., Sun, Xin, Khaleel, Mohammad A., & Qu, Jianmin. Global Failure Criteria for Positive/Electrolyte/Negative Structure of Planar Solid Oxide Fuel Cell. United States. doi:10.1016/j.jpowsour.2009.03.012.
Liu, Wenning N., Sun, Xin, Khaleel, Mohammad A., and Qu, Jianmin. 2009. "Global Failure Criteria for Positive/Electrolyte/Negative Structure of Planar Solid Oxide Fuel Cell". United States. doi:10.1016/j.jpowsour.2009.03.012.
@article{osti_964221,
title = {Global Failure Criteria for Positive/Electrolyte/Negative Structure of Planar Solid Oxide Fuel Cell},
author = {Liu, Wenning N. and Sun, Xin and Khaleel, Mohammad A. and Qu, Jianmin},
abstractNote = {Due to mismatch of the coefficients of thermal expansion of various layers in the positive/electrolyte/negative (PEN) structures of solid oxide fuel cells (SOFC), thermal stresses and warpage on the PEN are unavoidable due to the temperature changes from the stress-free sintering temperature to room temperature during the PEN manufacturing process. In the meantime, additional mechanical stresses will also be created by mechanical flattening during the stack assembly process. In order to ensure the structural integrity of the cell and stack of SOFC, it is necessary to develop failure criteria for SOFC PEN structures based on the initial flaws occurred during cell sintering and stack assembly. In this paper, the global relationship between the critical energy release rate and critical curvature and maximum displacement of the warped cells caused by the temperature changes as well as mechanical flattening process is established so that possible failure of SOFC PEN structures may be predicted deterministically by the measurement of the curvature and displacement of the warped cells.},
doi = {10.1016/j.jpowsour.2009.03.012},
journal = {Journal of Power Sources, 192(2):486-493},
number = ,
volume = ,
place = {United States},
year = 2009,
month = 7
}
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