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Title: The Antimony-Based Type I Clathrate compounds Cs8Cd18Sb28 and Cs8Zn18Sb28**

Abstract

The title compounds lie in a new region of phase space for such a structure, and have stoichiometries in accord with a classical Zintl phase formulation. The small semiconductor gaps indicated by DFT calculations are also supported by their diamagnetic susceptibilities.

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
963977
Report Number(s):
IS-J 7505
Journal ID: 1521-3773; TRN: US200918%%420
DOE Contract Number:
DE-AC02-07CH11358
Resource Type:
Journal Article
Resource Relation:
Journal Name: Angewandte Chemie; Journal Volume: 48; Journal Issue: 29
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CLATHRATES; PHASE SPACE; CHEMISTRY

Citation Formats

Liu, Yi, Wu, Li-Ming, Li, Long-Hua, Du, Shao-Wu, Corbett, John D., and Chen, Ling. The Antimony-Based Type I Clathrate compounds Cs8Cd18Sb28 and Cs8Zn18Sb28**. United States: N. p., 2009. Web. doi:10.1002/anie.200806158.
Liu, Yi, Wu, Li-Ming, Li, Long-Hua, Du, Shao-Wu, Corbett, John D., & Chen, Ling. The Antimony-Based Type I Clathrate compounds Cs8Cd18Sb28 and Cs8Zn18Sb28**. United States. doi:10.1002/anie.200806158.
Liu, Yi, Wu, Li-Ming, Li, Long-Hua, Du, Shao-Wu, Corbett, John D., and Chen, Ling. Wed . "The Antimony-Based Type I Clathrate compounds Cs8Cd18Sb28 and Cs8Zn18Sb28**". United States. doi:10.1002/anie.200806158.
@article{osti_963977,
title = {The Antimony-Based Type I Clathrate compounds Cs8Cd18Sb28 and Cs8Zn18Sb28**},
author = {Liu, Yi and Wu, Li-Ming and Li, Long-Hua and Du, Shao-Wu and Corbett, John D. and Chen, Ling},
abstractNote = {The title compounds lie in a new region of phase space for such a structure, and have stoichiometries in accord with a classical Zintl phase formulation. The small semiconductor gaps indicated by DFT calculations are also supported by their diamagnetic susceptibilities.},
doi = {10.1002/anie.200806158},
journal = {Angewandte Chemie},
number = 29,
volume = 48,
place = {United States},
year = {Wed Jun 17 00:00:00 EDT 2009},
month = {Wed Jun 17 00:00:00 EDT 2009}
}