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Title: Electronic Structure of the Organic Semiconductor Vanadyl Phthalocyanine (VO-Pc)

Abstract

The electronic structure of thin films of the organic semiconductor vanadyl phthalocyanine has been studied using synchrotron radiation-excited resonant soft X-ray emission spectroscopy, resonant inelastic soft X-ray scattering, X-ray absorption spectroscopy, and X-ray photoemission spectroscopy. The C, N, V, and O partial densities of states for both the valence and conduction bands have been determined, as well as the core level electronic structure. Good agreement was found between the experimental measurements of the valence and conduction bands, and the results of a density functional calculation.

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL) National Synchrotron Light Source
Sponsoring Org.:
Doe - Office Of Science
OSTI Identifier:
960053
Report Number(s):
BNL-83039-2009-JA
Journal ID: ISSN 0959-9428; JMACEP; TRN: US201016%%1197
DOE Contract Number:  
DE-AC02-98CH10886
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Materials Chemistry; Journal Volume: 17
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; ELECTRONIC STRUCTURE; EMISSION SPECTROSCOPY; FUNCTIONALS; ORGANIC SEMICONDUCTORS; PHOTOEMISSION; PHTHALOCYANINES; SCATTERING; SPECTROSCOPY; SYNCHROTRONS; THIN FILMS; VALENCE; national synchrotron light source

Citation Formats

Zhang,Y., Learmonth, T., Wang, S., Matsura, A., Downes, J., Plucinski, L., Bernardis, S., O'Donnell, C., and Smith, K. Electronic Structure of the Organic Semiconductor Vanadyl Phthalocyanine (VO-Pc). United States: N. p., 2007. Web. doi:10.1039/b613274j.
Zhang,Y., Learmonth, T., Wang, S., Matsura, A., Downes, J., Plucinski, L., Bernardis, S., O'Donnell, C., & Smith, K. Electronic Structure of the Organic Semiconductor Vanadyl Phthalocyanine (VO-Pc). United States. doi:10.1039/b613274j.
Zhang,Y., Learmonth, T., Wang, S., Matsura, A., Downes, J., Plucinski, L., Bernardis, S., O'Donnell, C., and Smith, K. Mon . "Electronic Structure of the Organic Semiconductor Vanadyl Phthalocyanine (VO-Pc)". United States. doi:10.1039/b613274j.
@article{osti_960053,
title = {Electronic Structure of the Organic Semiconductor Vanadyl Phthalocyanine (VO-Pc)},
author = {Zhang,Y. and Learmonth, T. and Wang, S. and Matsura, A. and Downes, J. and Plucinski, L. and Bernardis, S. and O'Donnell, C. and Smith, K.},
abstractNote = {The electronic structure of thin films of the organic semiconductor vanadyl phthalocyanine has been studied using synchrotron radiation-excited resonant soft X-ray emission spectroscopy, resonant inelastic soft X-ray scattering, X-ray absorption spectroscopy, and X-ray photoemission spectroscopy. The C, N, V, and O partial densities of states for both the valence and conduction bands have been determined, as well as the core level electronic structure. Good agreement was found between the experimental measurements of the valence and conduction bands, and the results of a density functional calculation.},
doi = {10.1039/b613274j},
journal = {Journal of Materials Chemistry},
number = ,
volume = 17,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}