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Title: Crystal Structure and Phase Transitions of Sr2CdWO6

Abstract

The crystal structure of Sr2CdWO6, prepared by solid state reaction, was determined by high-resolution X-ray diffraction at different temperatures. At room temperature, this compound has a monoclinic structure (space group P21/n) with a=5.7463(1), b=5.8189(1), c=8.1465(1), {beta}=90.071(1). At 1105 K the structure is converted to tetragonal (space group I4/m). Diffraction data also suggest that a cubic phase exists above 1220 K. Comparing the phase transition temperatures of Sr2CdWO6 with those of other compounds of the Sr2MWO6 family reported previously, it was observed that the transition temperatures are higher in compounds with low-tolerance factors. At the same time, the temperature range in which the intermediate tetragonal phase exists is reduced.

Authors:
; ;
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL) National Synchrotron Light Source
Sponsoring Org.:
Doe - Office Of Science
OSTI Identifier:
959915
Report Number(s):
BNL-82901-2009-JA
Journal ID: ISSN 0022-4596; JSSCBI; TRN: US201016%%1059
DOE Contract Number:  
DE-AC02-98CH10886
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 180
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CRYSTAL STRUCTURE; DIFFRACTION; TRANSITION TEMPERATURE; X-RAY DIFFRACTION; national synchrotron light source

Citation Formats

Gateshki,M., Igartua, J., and Faik, A.. Crystal Structure and Phase Transitions of Sr2CdWO6. United States: N. p., 2007. Web. doi:10.1016/j.jssc.2007.05.022.
Gateshki,M., Igartua, J., & Faik, A.. Crystal Structure and Phase Transitions of Sr2CdWO6. United States. doi:10.1016/j.jssc.2007.05.022.
Gateshki,M., Igartua, J., and Faik, A.. Mon . "Crystal Structure and Phase Transitions of Sr2CdWO6". United States. doi:10.1016/j.jssc.2007.05.022.
@article{osti_959915,
title = {Crystal Structure and Phase Transitions of Sr2CdWO6},
author = {Gateshki,M. and Igartua, J. and Faik, A.},
abstractNote = {The crystal structure of Sr2CdWO6, prepared by solid state reaction, was determined by high-resolution X-ray diffraction at different temperatures. At room temperature, this compound has a monoclinic structure (space group P21/n) with a=5.7463(1), b=5.8189(1), c=8.1465(1), {beta}=90.071(1). At 1105 K the structure is converted to tetragonal (space group I4/m). Diffraction data also suggest that a cubic phase exists above 1220 K. Comparing the phase transition temperatures of Sr2CdWO6 with those of other compounds of the Sr2MWO6 family reported previously, it was observed that the transition temperatures are higher in compounds with low-tolerance factors. At the same time, the temperature range in which the intermediate tetragonal phase exists is reduced.},
doi = {10.1016/j.jssc.2007.05.022},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 180,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}