An Electron Transfer Series of High-Valent Chromium Complexes With Redox Non-Innocent, Non-Heme Ligands
Journal Article
·
· Angew. Chem. Int. Ed. 47:6384,2008
OSTI ID:953095
An investigation of the electronic interplay between ligand radical(s) and a high-valent metal center in the three-member electron-transfer series shown in the picture reveals that, upon oxidation and removal of both ligand radicals, the chromium center becomes reduced from Cr{sup IV} to Cr{sup III} with concomitant formation of an imidyl radical (NR{center_dot}){sup -}.
- Research Organization:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-76SF00515
- OSTI ID:
- 953095
- Report Number(s):
- SLAC-REPRINT-2009-189; ACIEAY; TRN: US200914%%194
- Journal Information:
- Angew. Chem. Int. Ed. 47:6384,2008, Vol. 47, Issue 34; ISSN 0570-0833
- Country of Publication:
- United States
- Language:
- English
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