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Title: CuF{sub 2}(H{sub 2}O){sub 2} (pyz = pyrazine) : long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF{sub 2}{sup -} pyrazine ligands.

Abstract

[Cu(HF{sub 2})(pyz){sub 2}]BF{sub 4} consists of rare {mu}{sub 1,3} bridging HF{sub 2}{sup -} anions and {mu}-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.

Authors:
; ; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC); Engineering and Physical Sciences Research Council (EPSRC); 1851 Commission (UK)
OSTI Identifier:
948801
Report Number(s):
ANL/MSD/JA-58625
Journal ID: ISSN 1359-7345; TRN: US200907%%203
DOE Contract Number:
DE-AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chem. Commun.; Journal Issue: 47 ; 2006
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; COPPER COMPLEXES; POLYMERS; PYRAZINES; HYDROFLUORIC ACID; MOLECULAR STRUCTURE; ANTIFERROMAGNETISM; ORDER PARAMETERS

Citation Formats

Manson, J. L., Connor, M. M., Schlueter, J. A., McConnell, A. C., Southerland, H. I., Malfant, I., Lancaster, T., Blundell, S. J., Brooks, M. L., Pratt, F. L., Materials Science Division, Maitre de Conferences de l'Univ. Paul Sabatier, Oxford Univ., and Rutherford Appleton Lab.. CuF{sub 2}(H{sub 2}O){sub 2} (pyz = pyrazine) : long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF{sub 2}{sup -} pyrazine ligands.. United States: N. p., 2006. Web. doi:10.1039/b608791d.
Manson, J. L., Connor, M. M., Schlueter, J. A., McConnell, A. C., Southerland, H. I., Malfant, I., Lancaster, T., Blundell, S. J., Brooks, M. L., Pratt, F. L., Materials Science Division, Maitre de Conferences de l'Univ. Paul Sabatier, Oxford Univ., & Rutherford Appleton Lab.. CuF{sub 2}(H{sub 2}O){sub 2} (pyz = pyrazine) : long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF{sub 2}{sup -} pyrazine ligands.. United States. doi:10.1039/b608791d.
Manson, J. L., Connor, M. M., Schlueter, J. A., McConnell, A. C., Southerland, H. I., Malfant, I., Lancaster, T., Blundell, S. J., Brooks, M. L., Pratt, F. L., Materials Science Division, Maitre de Conferences de l'Univ. Paul Sabatier, Oxford Univ., and Rutherford Appleton Lab.. Sun . "CuF{sub 2}(H{sub 2}O){sub 2} (pyz = pyrazine) : long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF{sub 2}{sup -} pyrazine ligands.". United States. doi:10.1039/b608791d.
@article{osti_948801,
title = {CuF{sub 2}(H{sub 2}O){sub 2} (pyz = pyrazine) : long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF{sub 2}{sup -} pyrazine ligands.},
author = {Manson, J. L. and Connor, M. M. and Schlueter, J. A. and McConnell, A. C. and Southerland, H. I. and Malfant, I. and Lancaster, T. and Blundell, S. J. and Brooks, M. L. and Pratt, F. L. and Materials Science Division and Maitre de Conferences de l'Univ. Paul Sabatier and Oxford Univ. and Rutherford Appleton Lab.},
abstractNote = {[Cu(HF{sub 2})(pyz){sub 2}]BF{sub 4} consists of rare {mu}{sub 1,3} bridging HF{sub 2}{sup -} anions and {mu}-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.},
doi = {10.1039/b608791d},
journal = {Chem. Commun.},
number = 47 ; 2006,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 2006},
month = {Sun Jan 01 00:00:00 EST 2006}
}