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Title: Dependence of Polymer Hybrid Photovoltaic Performance on Donor-Acceptor Morphology

Conference ·
OSTI ID:943993

In this paper, we present our experimental and numerical studies on polymer-polymer and polymer-inorganic hybrid photovoltaic cells as the donor-acceptor morphology evolves from sharply defined layers, to partial blends and finally homogeneous blends. Results are compared for polyphenylene-vinylene (PPV) polymer donors and a variety of electron accepting materials, including CN-ether PPV, PCBM, and titanium dioxide. We show that optimal device performance is achieved by combining blended and layered structures and by tuning exciton generation rate position by controlling thickness.

Research Organization:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-99-GO10337
OSTI ID:
943993
Resource Relation:
Conference: [Proceedings] 2006 IEEE 4th World Conference on Photovoltaic Energy Conversion (WCPEC-4), 7-12 May 2006, Waikoloa, Hawaii
Country of Publication:
United States
Language:
English