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Title: Bis[bis(triphenylphosphoranylidene)ammonium]{mu}-tetrathiaoxalato-bis [(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(II)].

Abstract

The binuclear complex anion in [(C6H5)(6)P2N](2)[(C3S5)Ni(C2S4)Ni(C3S5)], conventionally abbreviated (PPN)(2)[(dmit)Ni(tto)Ni(dmit)], where PPN is bis(triphenylphosphoranylidene)ammonium, dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate and tto is tetrathiaoxalate, is centrosymmetric and essentially planar, except for a small twist of 2.7(1)degrees at the Ni centers. The bond lengths [average Ni-S distance 2.166(8) Angstrom] and angles are comparable to those reported elsewhere for other salts of the component ions. The crystal packing and the charge state of the complex anion are not favorable for electrical conduction. The binuclear complex anion was synthesized by a simpler method than that published previously.

Authors:
; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
942448
Report Number(s):
ANL/CHM/JA-31548
Journal ID: ISSN 0108-2701; ACSCEE; TRN: US200916%%533
DOE Contract Number:  
DE-AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Acta Crystallogr. C
Additional Journal Information:
Journal Volume: 55; Journal Issue: Pt. 8 ; Aug. 15, 1999; Journal ID: ISSN 0108-2701
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; ANIONS; BOND LENGTHS; CHARGE STATES; CRYSTALS; CRYSTAL STRUCTURE; IONS; SALTS

Citation Formats

Geiser, U., Mercuri, M. L., Parakka, J. P., and Chemistry. Bis[bis(triphenylphosphoranylidene)ammonium]{mu}-tetrathiaoxalato-bis [(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(II)].. United States: N. p., 1999. Web. doi:10.1107/S0108270199004692.
Geiser, U., Mercuri, M. L., Parakka, J. P., & Chemistry. Bis[bis(triphenylphosphoranylidene)ammonium]{mu}-tetrathiaoxalato-bis [(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(II)].. United States. doi:10.1107/S0108270199004692.
Geiser, U., Mercuri, M. L., Parakka, J. P., and Chemistry. Sun . "Bis[bis(triphenylphosphoranylidene)ammonium]{mu}-tetrathiaoxalato-bis [(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(II)].". United States. doi:10.1107/S0108270199004692.
@article{osti_942448,
title = {Bis[bis(triphenylphosphoranylidene)ammonium]{mu}-tetrathiaoxalato-bis [(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(II)].},
author = {Geiser, U. and Mercuri, M. L. and Parakka, J. P. and Chemistry},
abstractNote = {The binuclear complex anion in [(C6H5)(6)P2N](2)[(C3S5)Ni(C2S4)Ni(C3S5)], conventionally abbreviated (PPN)(2)[(dmit)Ni(tto)Ni(dmit)], where PPN is bis(triphenylphosphoranylidene)ammonium, dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate and tto is tetrathiaoxalate, is centrosymmetric and essentially planar, except for a small twist of 2.7(1)degrees at the Ni centers. The bond lengths [average Ni-S distance 2.166(8) Angstrom] and angles are comparable to those reported elsewhere for other salts of the component ions. The crystal packing and the charge state of the complex anion are not favorable for electrical conduction. The binuclear complex anion was synthesized by a simpler method than that published previously.},
doi = {10.1107/S0108270199004692},
journal = {Acta Crystallogr. C},
issn = {0108-2701},
number = Pt. 8 ; Aug. 15, 1999,
volume = 55,
place = {United States},
year = {1999},
month = {8}
}