Organocatalytic Stereoselective Ring-Opening Polymerization of Lactide with Dimeric Phosphazene Bases
Journal Article
·
· Journal of the American Chemical Society
- Almaden Research Center
- ORNL
Highly isotactic polylactide with a high melting temperature was synthesized from rac-lactide through an organocatalytic route using dimeric phosphazene base 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-2 5,4 5-catenadi(phosphazene) (P2-t-Bu) catalyst at low temperature. Microstructural analysis of the prepared polymer using homodecoupled 1H NMR spectroscopy revealed the formation of a stereoblock architecture containing long isotactic sequence of R- and S- blocks in the main chain. A proposed mechanism involving chain-end control and stereoerror explains the stereoselective polymerization.
- Research Organization:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC05-00OR22725
- OSTI ID:
- 940792
- Journal Information:
- Journal of the American Chemical Society, Vol. 129, Issue 42; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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