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Title: A novel pseudo-2D structural motif in an anionic copper(II) dicyanamide coordination polymer.

Abstract

Anionic coordination polymers of divalent first-row transition elements are promising components of multifunctional molecular materials in which electronic conduction and magnetism can coexist. We report that a tetraphenylphosphonium salt containing a copper(II) dicyanamide anion has a novel pseudo-two-dimensional anionic structure and may provide a suitable electrolyte for the electrocrystallization of charge transfer salts. This (PPh{sub 4}){sub 3}Cu{sub 4}(dca){sub 11} salt crystallizes in the monoclinic space group P2{sub 1} with lattice parameters, a = 7.1911(4) {angstrom}, = 55.050(3) {angstrom}, c = 11.7964(7) {angstrom}, {beta} = 99.166(3){sup o} and V = 4610.2(7) {angstrom}{sup 3} at T = 298 K.

Authors:
; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
940702
Report Number(s):
ANL/MSD/JA-57833
Journal ID: ISSN 1631-0748; TRN: US200824%%178
DOE Contract Number:  
DE-AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: C. R. Chimie; Journal Volume: 10; Journal Issue: 1-2 ; 2007
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; ANIONS; ELECTROLYTES; LATTICE PARAMETERS; MAGNETISM; POLYMERS; COPPER COMPOUNDS; CYANIDES; CRYSTALLIZATION

Citation Formats

Schlueter, J. A., Manson, J. L., Geiser, U., Materials Science Division, and Eastern Washington Univ.. A novel pseudo-2D structural motif in an anionic copper(II) dicyanamide coordination polymer.. United States: N. p., 2007. Web. doi:10.1016/j.crci.2006.06.011.
Schlueter, J. A., Manson, J. L., Geiser, U., Materials Science Division, & Eastern Washington Univ.. A novel pseudo-2D structural motif in an anionic copper(II) dicyanamide coordination polymer.. United States. doi:10.1016/j.crci.2006.06.011.
Schlueter, J. A., Manson, J. L., Geiser, U., Materials Science Division, and Eastern Washington Univ.. Mon . "A novel pseudo-2D structural motif in an anionic copper(II) dicyanamide coordination polymer.". United States. doi:10.1016/j.crci.2006.06.011.
@article{osti_940702,
title = {A novel pseudo-2D structural motif in an anionic copper(II) dicyanamide coordination polymer.},
author = {Schlueter, J. A. and Manson, J. L. and Geiser, U. and Materials Science Division and Eastern Washington Univ.},
abstractNote = {Anionic coordination polymers of divalent first-row transition elements are promising components of multifunctional molecular materials in which electronic conduction and magnetism can coexist. We report that a tetraphenylphosphonium salt containing a copper(II) dicyanamide anion has a novel pseudo-two-dimensional anionic structure and may provide a suitable electrolyte for the electrocrystallization of charge transfer salts. This (PPh{sub 4}){sub 3}Cu{sub 4}(dca){sub 11} salt crystallizes in the monoclinic space group P2{sub 1} with lattice parameters, a = 7.1911(4) {angstrom}, = 55.050(3) {angstrom}, c = 11.7964(7) {angstrom}, {beta} = 99.166(3){sup o} and V = 4610.2(7) {angstrom}{sup 3} at T = 298 K.},
doi = {10.1016/j.crci.2006.06.011},
journal = {C. R. Chimie},
number = 1-2 ; 2007,
volume = 10,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}