Zeolite catalysis studied by radiolysis/EPR. Transformations of cyclic olefins.
The Br{o}nsted acid-catalyzed transformations of cyclic olefins in zeolites HZSM5 and H-mordenite were elucidated by the radiolysis/EPR method. Products of catalytic reactions were spin- labeled by radiolytic means and identified by using EPR spectroscopy. Comparison of reactions on HZSM5 and H-mordenite reveals strong shape selectivity on reactions in these catalysts. The radiolysis/EPR method is a new in situ spectroscopy with excellent sensitivity and structural specificity for the study of reaction mechanisms in zeolite catalysts.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- ER
- DOE Contract Number:
- DE-AC02-06CH11357
- OSTI ID:
- 937963
- Report Number(s):
- ANL/CHM/JA-24841; CALEER; TRN: US200905%%616
- Journal Information:
- Catal. Lett., Vol. 45, Issue 1997; ISSN 1011-372X
- Country of Publication:
- United States
- Language:
- ENGLISH
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