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Title: Cd, Hg, and Pb Compounds of Benzene-1,3-diamidoethanethiol (BDETH2)

Abstract

Benzene-1,3-diamidoethanethiol (BDETH{sub 2}) is an exceptional precipitant for removing soft heavy metals from water. The present work will detail the bonding arrangement of BDETH{sub 2} to the metals Cd, Hg, and Pb, along with the full characterization data of the BDET-M compounds. It was found that the Hg compound has a linear S-M-S geometry. The characterization data consisted of Mp, EA, IR, Raman, MS, XANES, EXAFS, and solid-state multinuclear NMR.

Authors:
; ; ;
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL) National Synchrotron Light Source
Sponsoring Org.:
Doe - Office Of Science
OSTI Identifier:
930379
Report Number(s):
BNL-81101-2008-JA
Journal ID: ISSN 0020-1669; INOCAJ; TRN: US200904%%530
DOE Contract Number:  
DE-AC02-98CH10886
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorganic Chemistry; Journal Volume: 46
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; CADMIUM COMPLEXES; MERCURY COMPLEXES; LEAD COMPLEXES; THIOLS; AROMATICS; WATER TREATMENT; DEMETALLIZATION; national synchrotron light source

Citation Formats

Zaman,K., Blue, L., Huggins, F., and Atwood, D.. Cd, Hg, and Pb Compounds of Benzene-1,3-diamidoethanethiol (BDETH2). United States: N. p., 2007. Web. doi:10.1021/ic0607639.
Zaman,K., Blue, L., Huggins, F., & Atwood, D.. Cd, Hg, and Pb Compounds of Benzene-1,3-diamidoethanethiol (BDETH2). United States. doi:10.1021/ic0607639.
Zaman,K., Blue, L., Huggins, F., and Atwood, D.. Mon . "Cd, Hg, and Pb Compounds of Benzene-1,3-diamidoethanethiol (BDETH2)". United States. doi:10.1021/ic0607639.
@article{osti_930379,
title = {Cd, Hg, and Pb Compounds of Benzene-1,3-diamidoethanethiol (BDETH2)},
author = {Zaman,K. and Blue, L. and Huggins, F. and Atwood, D.},
abstractNote = {Benzene-1,3-diamidoethanethiol (BDETH{sub 2}) is an exceptional precipitant for removing soft heavy metals from water. The present work will detail the bonding arrangement of BDETH{sub 2} to the metals Cd, Hg, and Pb, along with the full characterization data of the BDET-M compounds. It was found that the Hg compound has a linear S-M-S geometry. The characterization data consisted of Mp, EA, IR, Raman, MS, XANES, EXAFS, and solid-state multinuclear NMR.},
doi = {10.1021/ic0607639},
journal = {Inorganic Chemistry},
number = ,
volume = 46,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}