Comparison of the results of short-term static tests and single-pass flow-through tests with LRM glass.
Static dissolution tests were conducted to measure the forward dissolution rate of LRM glass at 70 C and pH(RT) 11.7 {+-} 0.1 for comparison with the rate measured with single-pass flow-through (SPFT) tests in an interlaboratory study (ILS). The static tests were conducted with monolithic specimens having known geometric surface areas, whereas the SPFT tests were conducted with crushed glass that had an uncertain specific surface area. The error in the specific surface area of the crushed glass used in the SPFT tests, which was calculated by modeling the particles as spheres, was assessed based on the difference in the forward dissolution rates measured with the two test methods. Three series of static tests were conducted at 70 C following ASTM standard test method C1220 using specimens with surfaces polished to 600, 800, and 1200 grit and a leachant solution having the same composition as that used in the ILS. Regression of the combined results of the static tests to the affinity-based glass dissolution model gives a forward rate of 1.67 g/(m{sup 2}d). The mean value of the forward rate from the SPFT tests was 1.64 g/(m{sup 2}d) with an extended uncertainty of 1.90 g/(m{sup 2}d). This indicates that the calculated surface area for the crushed glass used in the SPFT tests is less than 2% higher than the actual surface area, which is well within the experimental uncertainties of measuring the forward dissolution rate using each test method. These results indicate that the geometric surface area of crushed glass calculated based on the size of the sieves used to isolate the fraction used in a test is reliable. In addition, the C1220 test method provides a means for measuring the forward dissolution rate of borosilicate glasses that is faster, easier, and more economical than the SPFT test method.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 925334
- Report Number(s):
- ANL-06/51
- Country of Publication:
- United States
- Language:
- ENGLISH
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