Templated synthesis of pyridine functionalized mesoporous carbons through the cyclotrimerization of diethynylpyridines
Journal Article
·
· Chemistry of Materials, 20(3):981-986
Templated mesoporous carbons designed around the pyridine functionality have been made using the cyclotrimerization of a variety of diethynylpyridines. The substitution pattern of the ethynyl moieties about the pyridine ring system was found to have a significant impact on the structure and properties of the final product. A model is proposed that focuses on the self-assembly of the diethynylpyridine monomer on the silica surface, and the order and orientation of the ethynyl moieties within this monolayer.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 924670
- Report Number(s):
- PNNL-SA-54865; CMATEX; TRN: US200809%%324
- Journal Information:
- Chemistry of Materials, 20(3):981-986, Vol. 20, Issue 3; ISSN 0897-4756
- Country of Publication:
- United States
- Language:
- English
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