EVALUATION OF IMPURITY EXTREMES IN A PLUTONIUM-LOADED BOROSILICATE GLASS
A vitrification technology utilizing a lanthanide borosilicate (LaBS) glass appears to be a viable option for the disposition of excess weapons-useable plutonium that is not suitable for processing into mixed oxide (MOX) fuel. A significant effort to develop a glass formulation and vitrification process to immobilize plutonium was completed in the mid-1990s. The LaBS glass formulation was found to be capable of immobilizing in excess of 10 wt % Pu and to be tolerant of a range of impurities. To confirm the results of previous testing with surrogate Pu feeds containing impurities, four glass compositions were selected for fabrication with actual plutonium oxide and impurities. The four compositions represented extremes in impurity type and concentration. The homogeneity and durability of these four compositions were measured. The homogeneity of the glasses was evaluated using x-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS). The XRD results indicated that the glasses were amorphous with no evidence of crystalline species in the glass. The SEM/EDS analyses did show the presence of some undissolved PuO{sub 2} material. The EDS spectra indicated that some of the PuO{sub 2} crystals also contained hafnium oxide. The SEM/EDS analyses showed that there were no heterogeneities in the glass due to the feed impurities. The durability of the glasses was measured using the Product Consistency Test (PCT). The PCT results indicated that the durability of Pu impurity glasses was comparable with Pu glasses without impurities and significantly more durable than the Environmental Assessment (EA) glass used as the benchmark for repository disposition of high-level waste (HLW) glasses.
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- DE-AC09-96SR18500
- OSTI ID:
- 921677
- Report Number(s):
- WSRC-STI-2007-00651; TRN: US0800794
- Resource Relation:
- Conference: Waste Management 2008
- Country of Publication:
- United States
- Language:
- English
Similar Records
GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE FRIT B COMPOSITION FOR PLUTONIUM DISPOSITION
GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE GLASS FOR PLUTONIUM DISPOSITION
Related Subjects
BENCHMARKS
BOROSILICATE GLASS
FABRICATION
GLASS
HAFNIUM OXIDES
IMPURITIES
OXIDES
PLUTONIUM
PLUTONIUM OXIDES
RARE EARTHS
SCANNING ELECTRON MICROSCOPY
SPECTRA
SPECTROSCOPY
VITRIFICATION
WASTE MANAGEMENT
WASTES
X-RAY DIFFRACTION