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Title: Single Source Molecular Precursors to Niobia-Silica and NiobiumPhosphate Materials

Abstract

The molecular precursors Nb(OiPr)2[OSi(OtBu)3]3 and {l_brace}Nb(OiPr)4[O2P(OtBu)2]{r_brace}2 have been prepared. The first compound undergoes facile thermal conversion to high surface area, acidic niobia silica, whereas the second one thermally decomposes to a low surface area niobium phosphate.

Authors:
;
Publication Date:
Research Org.:
Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
Sponsoring Org.:
USDOE Director. Office of Science. Basic EnergySciences
OSTI Identifier:
919833
Report Number(s):
LBNL-59614
Journal ID: ISSN 0026-9247; MOCHAP; R&D Project: 401701; BnR: KC0302010; TRN: US200822%%583
DOE Contract Number:
DE-AC02-05CH11231
Resource Type:
Journal Article
Resource Relation:
Journal Name: Monatshefte fur Chemie; Journal Volume: 137; Related Information: Journal Publication Date: 2006
Country of Publication:
United States
Language:
English
Subject:
37; NIOBIUM PHOSPHATES; SILICA; SURFACE AREA

Citation Formats

Lugmair, Claus G., and Tilley, T. Don. Single Source Molecular Precursors to Niobia-Silica and NiobiumPhosphate Materials. United States: N. p., 2006. Web. doi:10.1007/s00706-006-0445-9.
Lugmair, Claus G., & Tilley, T. Don. Single Source Molecular Precursors to Niobia-Silica and NiobiumPhosphate Materials. United States. doi:10.1007/s00706-006-0445-9.
Lugmair, Claus G., and Tilley, T. Don. Fri . "Single Source Molecular Precursors to Niobia-Silica and NiobiumPhosphate Materials". United States. doi:10.1007/s00706-006-0445-9.
@article{osti_919833,
title = {Single Source Molecular Precursors to Niobia-Silica and NiobiumPhosphate Materials},
author = {Lugmair, Claus G. and Tilley, T. Don},
abstractNote = {The molecular precursors Nb(OiPr)2[OSi(OtBu)3]3 and {l_brace}Nb(OiPr)4[O2P(OtBu)2]{r_brace}2 have been prepared. The first compound undergoes facile thermal conversion to high surface area, acidic niobia silica, whereas the second one thermally decomposes to a low surface area niobium phosphate.},
doi = {10.1007/s00706-006-0445-9},
journal = {Monatshefte fur Chemie},
number = ,
volume = 137,
place = {United States},
year = {Fri Jan 13 00:00:00 EST 2006},
month = {Fri Jan 13 00:00:00 EST 2006}
}